2,2':6',2''-Terpyridine, 4,4'',6,6''-tetraphenyl-

Base Information

Chemical Name:2,2':6',2''-Terpyridine, 4,4'',6,6''-tetraphenyl-
CAS No.:221055-92-1
Molecular Formula:C39H27N3
Molecular Weight:537.663
Hs Code.:
Mol file:221055-92-1.mol

Synonyms:

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Chemical Property of 2,2':6',2''-Terpyridine, 4,4'',6,6''-tetraphenyl-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of 2,2':6',2''-Terpyridine, 4,4'',6,6''-tetraphenyl-

There total 2 articles about 2,2':6',2''-Terpyridine, 4,4'',6,6''-tetraphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 16883-69-5
N-phenacylpyridinium bromide

: 132843-83-5
1,1'-(2,6-pyridylene)bis(3-phenyl-2-propen-1-one)

: 221055-92-1
4,6,4'',6''-Tetraphenyl-2,2':6',2''-terpyridine

Guidance literature:: With ammonium acetate; In methanol; for 16h; Heating;

Reference yield:

: 221055-92-1
4,6,4'',6''-Tetraphenyl-2,2':6',2''-terpyridine

Guidance literature:: 2,6-Dicinnamoylpyridin, /Z0265212281/;

Reference yield: 68.0%

: ammonium hexafluorophosphate

: 136276-24-9
[trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]

: 221055-92-1
4,6,4'',6''-Tetraphenyl-2,2':6',2''-terpyridine

: 402853-11-6
[Ru(N,N,C-4,6,4'',6''-tetraphenyl-2,2':6',2''-terpyridinato)(4'-p-tolyl-2,2':6',2''-terpyridine)]PF₆

: [Ru(4,6,4'',6''-tetraphenyl-2,2':6',2''-terpyridine)(4'-p-tolyl-2,2':6',2''-terpyridine)](PF₆)2*H₂O

Guidance literature:: With AgBF₄; In acetone; byproducts: AgCl; Ru complex added to AgBF4/acetone, refluxed under Ar for 30 min, filtered, DMF added to the filtrate, acetone removed (vac.), added to warmed ligand/DMF, refluxed in dark under Ar for 48 h, freed of solvent (vac.), dissolved in MeCN, aq. NH4PF6 added; triturated with MeOH, filtered, evapd.; a further amount obtained by chromy. (SiO2, MeCN/satd. KNO3/H2O) of the MeOH-insol. residue, the more polar fraction washed with H2O, re-pptd. with NH4PF6 as before, pptd. fromMeCN with Et2O; elem. anal.;
DOI:10.1016/S0020-1693(01)00626-0