Benzoic acid, cyclopropylMethyl ester

Base Information

• Chemical Name: Benzoic acid, cyclopropylMethyl ester
• CAS No.: 23293-79-0
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol file: 23293-79-0.mol

Synonyms:BENZOIC ACID, CYCLOPROPYLMETHYL ESTER;

Chemical Property of Benzoic acid, cyclopropylMethyl ester

Chemical Property:

• PSA: 26.30000
• LogP: 2.25340

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, cyclopropylMethyl ester

There total 11 articles about Benzoic acid, cyclopropylMethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Cyclopropylmethanol (2516-33-8) + N-methyl-N-phenyl-benzamide (1934-92-5) → cyclopropylmethyl benzoate (23293-79-0)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene; In toluene; at 80 ℃; for 12h;

DOI:10.1038/nature14615

Reference yield: 81.0%

(3-oxo-cyclobutyl)methyl benzoate (346425-59-0) → cyclopropylmethyl benzoate (23293-79-0) + vinyl benzoate (583-04-0)

Guidance literature:

In acetone; for 4h; Title compound not separated from byproducts; Photolysis;

DOI:10.1139/v00-175

Reference yield: 76.0%

Cyclopropylmethanol (2516-33-8) + benzyl alcohol (100-51-6,185532-71-2) → cyclopropylmethyl benzoate (23293-79-0)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; dichloro bis(acetonitrile) palladium(II); oxygen; potassium carbonate; at 80 ℃; for 12h; Schlenk technique;

DOI:10.1016/j.tet.2017.11.025

upstream raw materials:

Cyclopropylmethanol

benzoyl chloride

(2-bromoethyl)oxirane

(3-oxo-cyclobutyl)methyl benzoate