Benzene, [(1Z)-2-bromo-1,3-butadienyl]-

Base Information

• Chemical Name: Benzene, [(1Z)-2-bromo-1,3-butadienyl]-
• CAS No.: 24182-36-3
• Molecular Formula: C10H9Br
• Molecular Weight: 209.085
• Mol file: 24182-36-3.mol

Synonyms:(Z)-3-bromo-4-phenyl-1,3-butadiene;[(Z)-2-bromobuta-1,3-dienyl]benzene;(Z)-2-bromo-1-phenyl-1,3-butadiene;Benzene,[(1Z)-2-bromo-1,3-butadienyl];(Z)-(2-bromobuta-1,3-dien-1-yl)benzene;cis-3-bromo-4-phenyl-1,3-butadiene;

Chemical Property of Benzene, [(1Z)-2-bromo-1,3-butadienyl]-

Chemical Property:

• PSA: 0.00000
• LogP: 3.60840

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene, [(1Z)-2-bromo-1,3-butadienyl]-

There total 14 articles about Benzene, [(1Z)-2-bromo-1,3-butadienyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2,2-dibromostyrene (7436-90-0) + vinyl zinc chloride (78389-90-9) → [(1Z)-2-bromobuta-1,3-dien-1-yl]benzene (24182-36-3)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1002/(SICI)1521-3773(20000317)39:6<1042::AID-ANIE1042>3.0.CO;2-7

Reference yield: 75.0%

2,2-dibromostyrene (7436-90-0) + tri-n-butyl(vinyl)tin (7486-35-3) → [(1Z)-2-bromobuta-1,3-dien-1-yl]benzene (24182-36-3)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; at 100 ℃; for 20h;

DOI:10.1021/jo991116k

Reference yield: 66.0%

trans-1,1-dibromo-2-phenyl-3-(trimethylsilylmethyl)cyclopropane → [(1Z)-2-bromobuta-1,3-dien-1-yl]benzene (24182-36-3)

Guidance literature:

at 150 - 180 ℃; Thermolysis;

DOI:10.1021/jo050142h

upstream raw materials:

(2Z)-2-bromo-3-phenyl-2-propenal

methyl-triphenylphosphonium iodide

2,2-dibromostyrene

tri-n-butyl(vinyl)tin

Downstream raw materials:

4-phenylbut-1-en-3-yne

(E)-2-Bromo-1-phenyl-1,3-butadiene

(E)-2-methoxy-1-phenylbuta-1,3-diene

(Z)-2-Methoxy-1-phenyl-1,3-butadiene