Benzenamine, N-(1-methylethyl)-N-nitroso-

Base Information

• Chemical Name: Benzenamine, N-(1-methylethyl)-N-nitroso-
• CAS No.: 24642-83-9
• Molecular Formula: C9H12N2O
• Molecular Weight: 164.207
• DSSTox Substance ID: DTXSID10482373
• Wikidata: Q82318621
• Mol file: 24642-83-9.mol

Synonyms:24642-83-9;Benzenamine, N-(1-methylethyl)-N-nitroso-;N-phenyl-N-propan-2-ylnitrous amide;N-nitroso-N-isopropylaniline;SCHEMBL11355172;DTXSID10482373;N-nitroso-N-(propan-2-yl)aniline;EN300-27716329

Chemical Property of Benzenamine, N-(1-methylethyl)-N-nitroso-

Chemical Property:

• Boiling Point: 273.8±13.0 °C(Predicted)
• PSA: 32.67000
• Density: 1.02±0.1 g/cm3(Predicted)
• LogP: 2.58280
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 164.094963011
• Heavy Atom Count: 12
• Complexity: 142

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)N(C1=CC=CC=C1)N=O

Technology Process of Benzenamine, N-(1-methylethyl)-N-nitroso-

There total 4 articles about Benzenamine, N-(1-methylethyl)-N-nitroso- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

N-Isopropylaniline (768-52-5) → N-isopropyl-N-phenylnitrous amide (24642-83-9)

Guidance literature:

N-Isopropylaniline; With hydrogenchloride; In water; acetonitrile; at 0 ℃;

With sodium nitrite; In water; acetonitrile;

DOI:10.1021/ol402523x

Reference yield: 18.0%

C21H24CuN4(2+)*2ClO4(1-) → N-isopropyl-N-phenylnitrous amide (24642-83-9) + Acetanilid (103-84-4)

Guidance literature:

With nitrogen(II) oxide; In acetonitrile; for 0.166667h; Schlenk technique;

Reference yield:

N-Isopropylaniline (768-52-5) + isopentyl nitrite (110-46-3) → N-isopropyl-N-phenylnitrous amide (24642-83-9)

Guidance literature:

With 4-(1,1-dimethylethyl)benzoic acid; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere; Glovebox; Schlenk technique;

DOI:10.1039/c9cc04529e

upstream raw materials:

N-Isopropylaniline

isopentyl nitrite

Downstream raw materials:

1-(1-Methylethyl)-1-phenylhydrazine