Methyl 10,11-dihydroxyundecanoate

Base Information

• Chemical Name: Methyl 10,11-dihydroxyundecanoate
• CAS No.: 24724-06-9
• Molecular Formula: C12H24O4
• Molecular Weight: 232.32
• DSSTox Substance ID: DTXSID70399256
• Nikkaji Number: J1.549.510C
• Mol file: 24724-06-9.mol

Synonyms:24724-06-9;Methyl 10,11-dihydroxyundecanoate;Undecanoic acid, 10,11-dihydroxy-, methyl ester;SCHEMBL9307282;DTXSID70399256;AKOS024366457;10,11-Dihydroxyundecanoic acid methyl ester

Chemical Property of Methyl 10,11-dihydroxyundecanoate

Chemical Property:

• XLogP3: 2
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 11
• Exact Mass: 232.16745924
• Heavy Atom Count: 16
• Complexity: 170

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)CCCCCCCCC(CO)O

Technology Process of Methyl 10,11-dihydroxyundecanoate

There total 3 articles about Methyl 10,11-dihydroxyundecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

Methyl 10-undecenoate (111-81-9) → 10-oxo-decanoic acid methyl ester (14811-73-5) + methyl 10,11-dihydroxyundecanoate (24724-06-9)

Guidance literature:

With ruthenium trichloride; sodium periodate; In water; acetonitrile; at 20 ℃; for 1.5h;

DOI:10.1021/jo010122p

Reference yield: 44.0%

Methyl 10-undecenoate (111-81-9) → 10-oxo-decanoic acid methyl ester (14811-73-5) + methyl 10,11-dihydroxyundecanoate (24724-06-9) + sebacic acid mono methyl ester (818-88-2) + Methyl-10-keto-11-hydroxyundecanoat (56078-11-6)

Guidance literature:

With ruthenium trichloride; Oxone; sodium hydrogencarbonate; In water; acetonitrile; at 20 ℃; for 1.1h; Further Variations:; Solvents; Reagents; Product distribution;

DOI:10.1021/jo010122p

Reference yield:

aqueous sodium sulphite + Methyl 10-undecenoate (111-81-9) → methyl 10,11-dihydroxyundecanoate (24724-06-9) + sebacic acid mono methyl ester (818-88-2)

Guidance literature:

upstream raw materials:

Methyl 10-undecenoate

Downstream raw materials:

(3E, 13Z)-3,13-octadecadien-1-yl acetate

Methyl Z 10-pentadecenoate

10(Z)-pentadecen-1-yltriphenylphosphonium bromide

cis-10-pentadecenoic acid methyl ester