(2r)-6-Hydroxy-2-methyl-2h-pyran-3(6h)-one

Base Information

Chemical Name:(2r)-6-Hydroxy-2-methyl-2h-pyran-3(6h)-one
CAS No.:247244-64-0
Molecular Formula:C6H8O3
Molecular Weight:128.128
Hs Code.:
DSSTox Substance ID:DTXSID70452431
Nikkaji Number:J394.010A
Mol file:247244-64-0.mol

Synonyms:CTK0I7202;(2r)-6-hydroxy-2-methyl-2h-pyran-3(6h)-one;247244-64-0;DTXSID70452431;2alpha-Methyl-6-hydroxy-2H-pyran-3(6H)-one

Suppliers and Price of (2r)-6-Hydroxy-2-methyl-2h-pyran-3(6h)-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (2r)-6-Hydroxy-2-methyl-2h-pyran-3(6h)-one

Chemical Property:

XLogP3:-0.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:128.047344113
Heavy Atom Count:9
Complexity:150

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1C(=O)C=CC(O1)O
Isomeric SMILES:C[C@@H]1C(=O)C=CC(O1)O

Technology Process of (2r)-6-Hydroxy-2-methyl-2h-pyran-3(6h)-one

There total 2 articles about (2r)-6-Hydroxy-2-methyl-2h-pyran-3(6h)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 4208-64-4
1-(2-furyl)ethanol

: 27948-61-4
(R)-(+)-1-(2-furyl)ethanol

: 247244-64-0
(2R)-6-hydroxy-2-methyl-2H-pyran-3-(6H)-one

Guidance literature:: DOI:10.3987/COM-88-4690

Reference yield:

: 4208-64-4
1-(2-furyl)ethanol

: 4208-64-4,27948-61-4,106565-48-4,112653-32-4
(S)-1-(2-furanyl)ethanol

: 27948-61-4
(R)-(+)-1-(2-furyl)ethanol

: 247244-64-0
(2R)-6-hydroxy-2-methyl-2H-pyran-3-(6H)-one

Guidance literature:: With D-glucose; chloroperoxidase from Caldariomyces fumago; glucose oxidase type II from Aspergillus niger; In tert-butyl alcohol; at 30 ℃; for 0.166667h; pH=5.5; Enzymatic reaction;
DOI:10.1002/ejoc.201800333

Reference yield: 76.0%

: 103-82-2
phenylacetic acid

: 247244-64-0
(2R)-6-hydroxy-2-methyl-2H-pyran-3-(6H)-one

: (2R,6R)-6-methyl-5-oxo-5,6-dihydro-2H-pyran-2-yl 2-phenylacetate

Guidance literature:: With (R)-(+)-2-phenyl-2,3-dihydrobenzo[d]imidazo[2,1-b]thiazole; 2,2-dimethylpropanoic anhydride; N-ethyl-N,N-diisopropylamine; In chloroform; at 20 ℃; for 12h; Solvent; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/acs.orglett.5b02641