1-Butanone, 1,3,4-triphenyl-

Base Information

• Chemical Name: 1-Butanone, 1,3,4-triphenyl-
• CAS No.: 24892-77-1
• Molecular Formula: C22H20O
• Molecular Weight: 300.4
• DSSTox Substance ID: DTXSID20441552
• Nikkaji Number: J996.767B
• Mol file: 24892-77-1.mol

Synonyms:1,3,4-Triphenyl-1-butanone;1-Butanone, 1,3,4-triphenyl-;24892-77-1;SCHEMBL10033918;DTXSID20441552

Chemical Property of 1-Butanone, 1,3,4-triphenyl-

Chemical Property:

• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 300.151415257
• Heavy Atom Count: 23
• Complexity: 343

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CC(CC(=O)C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of 1-Butanone, 1,3,4-triphenyl-

There total 24 articles about 1-Butanone, 1,3,4-triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

bromobenzene (108-86-1,52753-63-6) + cis-1,3-diphenyl-1-cyclobutanol → 1,3,4-triphenylbutan-1-one (24892-77-1)

Guidance literature:

With N-methylcyclohexylamine; (S)-1-[(R)-2,2'-bis(Ph₂P)ferrocenyl]ethyl acetate; caesium carbonate; palladium diacetate; In toluene; at 80 ℃; for 24h;

DOI:10.1039/b107736h

Reference yield: 97.0%

benzyltributyltin (28493-54-1) + 1,3-diphenyl-propen-3-one (614-47-1) → 1,3,4-triphenylbutan-1-one (24892-77-1)

Guidance literature:

With tantalum pentachloride; In acetonitrile; at -40 ℃; for 2h;

DOI:10.1002/1521-3773(20020415)41:8<1389::AID-ANIE1389>3.0.CO;2-D

Reference yield: 97.0%

(3R,4R)-4-((R)-1H-Imidazole-2-sulfinyl)-1,3,4-triphenyl-butan-1-one → 1,3,4-triphenylbutan-1-one (24892-77-1)

Guidance literature:

With nickel; In ethanol; at 78 ℃; for 0.5h;

upstream raw materials:

1,3-diphenyl-propen-3-one

benzylmagnesium chloride

phenyl(1-phenylethylidene)amine

benzyl chloride

Downstream raw materials:

C₂₂H₂₀O