7-Phenylbicyclo[2.2.1]heptane

Base Information

Chemical Name:7-Phenylbicyclo[2.2.1]heptane
CAS No.:24892-78-2
Molecular Formula:C13H16
Molecular Weight:172.27
Hs Code.:
DSSTox Substance ID:DTXSID90496317
Nikkaji Number:J587.032A
Wikidata:Q82345084
Mol file:24892-78-2.mol

Synonyms:7-Phenylbicyclo[2.2.1]heptane;7-phenylnorbornane;24892-78-2;DTXSID90496317

Suppliers and Price of 7-Phenylbicyclo[2.2.1]heptane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 7-Phenylbicyclo[2.2.1]heptane

Chemical Property:

XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:172.125200510
Heavy Atom Count:13
Complexity:159

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2CCC1C2C3=CC=CC=C3

Technology Process of 7-Phenylbicyclo[2.2.1]heptane

There total 9 articles about 7-Phenylbicyclo[2.2.1]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 74200-29-6
(7-phenylnorbornyl)potassium

: 24892-78-2
7-phenylnorbornane

Guidance literature:: In methanol;
DOI:10.1021/ja00534a025

Reference yield: 51.0%

: 765-80-0
7-chlorobicyclo<2.2.1>heptane

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: 24892-78-2
7-phenylnorbornane

Guidance literature:: With aluminium trichloride; at -5 - 0 ℃; for 0.5h;
DOI:10.1021/jo00088a049

Reference yield:

: 875-04-7
7,7-dimethoxybicyclo<2.2.1>heptene

: 24892-78-2
7-phenylnorbornane

Guidance literature:: Multi-step reaction with 6 steps

2: tetrahydrofuran / -78 °C

3: 1.) sodium hydride / 1.) 0 deg C, 0.5 h, 2.) room temperature, 20 h

4: 95 percent / hydrogen / 10percent palladium on charcoal / ethyl acetate / 7 h

5: sodium/potassium alloy / tetrahydrofuran / 1 h / -10 - -5 °C / 0 Torr

6: 55 percent / methanol

With potassium alloy; hydrogen; sodium; sodium hydride; palladium on activated charcoal; In tetrahydrofuran; methanol; ethyl acetate;
DOI:10.1021/ja00534a025