Rhodium(1+), dicarbonyltris(triphenylarsine)-, perchlorate

Base Information

• Chemical Name: Rhodium(1+), dicarbonyltris(triphenylarsine)-, perchlorate
• CAS No.: 25300-55-4
• Molecular Formula: C₅₆H₄₅As₃O₂Rh*ClO₄
• Molecular Weight: 1177.09
• Mol file: 25300-55-4.mol

Synonyms:

Chemical Property of Rhodium(1+), dicarbonyltris(triphenylarsine)-, perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rhodium(1+), dicarbonyltris(triphenylarsine)-, perchlorate

There total 1 articles about Rhodium(1+), dicarbonyltris(triphenylarsine)-, perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Rh(3+)*3ClO4(1-)*99H2O=Rh(ClO4)3*99H2O + triphenyl-arsane (603-32-7) → [Rh(CO)2(As(C6H5)3)3](1+)*ClO4(1-)=[Rh(CO)2(As(C6H5)3)3]ClO4 (25300-55-4)

Guidance literature:

With carbon monoxide; In ethanol; freshly prepared hydrated Rh-perchlorate dissolved in abs. alcohol, CO gas passed throuh soln. under reflux for 15 min., AsPh3 added to refluxing soln., CO gas bubbled for another 1 h; soln. cooled, solvent removed under reduced pressure, crystn. on trituration with abs. alcohol, washed with abs. alcohol and benzene, stored over CaCl2 in a desiccator for drying, two isomers isolated;

Reference yield:

2.9-dimethyl-1,10-phenanthroline (484-11-7) + [Rh(CO)2(As(C6H5)3)3](1+)*ClO4(1-)=[Rh(CO)2(As(C6H5)3)3]ClO4 (25300-55-4) → [Rh(CO)(C12H6N2(CH3)2)(As(C6H5)3)2](1+)*ClO4(1-)=[Rh(CO)(C12H6N2(CH3)2)(As(C6H5)3)2]ClO4 (76032-27-4)

Guidance literature:

In ethanol; acetone; addn. of ligand to soln. of Rh-complex in alcohol/acetone, stirring for0.5 h, stored in a desiccator over CaCl2 for 4-5 h; soln. evapd. under vac., crystals washed with benzene, dried over CaCl2in a desiccator; elem. anal.;

Reference yield:

[Rh(CO)2(As(C6H5)3)3](1+)*ClO4(1-)=[Rh(CO)2(As(C6H5)3)3]ClO4 (25300-55-4) + 2,2'-biquinoline (119-91-5) → [Rh(CO)(C18H12N2)(As(C6H5)3)2](1+)*ClO4(1-)=[Rh(CO)(C18H12N2)(As(C6H5)3)2]ClO4 (69547-75-7)

Guidance literature:

In ethanol; acetone; addn. of ligand to soln. of Rh-complex in alcohol/acetone, stirring for0.5 h, stored in a desiccator over CaCl2 for 1 h; soln. evapd. under vac., crystals washed with benzene, dried over CaCl2in a desiccator; elem. anal.;

upstream raw materials:

triphenyl-arsane

Downstream raw materials:

[Rh(CO)(C₁₂H₆N₂(CH₃)2)(As(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₁₂H₆N₂(CH₃)2)(As(C₆H₅)3)2]ClO₄

[Rh(CO)(C₁₈H₁₂N₂)(As(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₁₈H₁₂N₂)(As(C₆H₅)3)2]ClO₄

[Rh(CO)(C₁₂H₄N₂(CH₃)2(C₆H₅)2)(As(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₁₂H₄N₂(CH₃)2(C₆H₅)2)(As(C₆H₅)3)2]ClO₄