Oxirane, [(2,3-dimethylphenoxy)methyl]-, (2S)-

Base Information

Chemical Name:Oxirane, [(2,3-dimethylphenoxy)methyl]-, (2S)-
CAS No.:256372-73-3
Molecular Formula:C11H14O2
Molecular Weight:178.231
Hs Code.:
DSSTox Substance ID:DTXSID10479369
Mol file:256372-73-3.mol

Synonyms:256372-73-3;Oxirane, [(2,3-dimethylphenoxy)methyl]-, (2S)-;SCHEMBL7966731;DTXSID10479369

Suppliers and Price of Oxirane, [(2,3-dimethylphenoxy)methyl]-, (2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Oxirane, [(2,3-dimethylphenoxy)methyl]-, (2S)-

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:178.099379685
Heavy Atom Count:13
Complexity:170

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C(=CC=C1)OCC2CO2)C
Isomeric SMILES:CC1=C(C(=CC=C1)OC[C@@H]2CO2)C

Technology Process of Oxirane, [(2,3-dimethylphenoxy)methyl]-, (2S)-

There total 7 articles about Oxirane, [(2,3-dimethylphenoxy)methyl]-, (2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.3%

: 850427-96-2
(R)-4-(2,3-Dimethyl-phenoxymethyl)-[1,3,2]dioxathiolane 2,2-dioxide

: 256372-73-3
(S)-1-(2',3'-dimethylphenoxy)-2,3-epoxypropane

Guidance literature:: (R)-4-(2,3-Dimethyl-phenoxymethyl)-[1,3,2]dioxathiolane 2,2-dioxide; With lithium bromide; In tetrahydrofuran; at 25 ℃;

With sulfuric acid; In diethyl ether; at 25 ℃;

With potassium carbonate; In methanol; at 0 ℃; for 2h;
DOI:10.1016/j.tet.2005.01.074

Reference yield: 47.0%

: 850427-86-0
(2S)-1-(2,3-dimethylphenoxy)-2,3-dihydroxypropane

: 256372-73-3
(S)-1-(2',3'-dimethylphenoxy)-2,3-epoxypropane

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; for 24h; Inert atmosphere; Reflux;
DOI:10.1016/j.tetasy.2017.08.013

Reference yield: 44.1%

: 41457-31-2
1,2-epoxy-3-[2,3-dimethylphenoxy]propane

: 256372-73-3
(S)-1-(2',3'-dimethylphenoxy)-2,3-epoxypropane

: (2R)-1-(2,3-dimethylphenoxy)-2,3-dihydroxypropane

Guidance literature:: With Bacillus megaterium epoxide hydrolase; In aq. phosphate buffer; di-isopropyl ether; at 25 ℃; pH=7; Enzymatic reaction;
DOI:10.1002/anie.201402653