Hydridotetrakis(triphenylphosphine)rhodium(I)

Base Information

• Chemical Name: Hydridotetrakis(triphenylphosphine)rhodium(I)
• CAS No.: 25869-38-9
• Molecular Formula: C₇₂H₆₀P₄Rh
• Molecular Weight: 1152.07
• European Community (EC) Number: 624-922-3
• DSSTox Substance ID: DTXSID90475127
• Wikipedia: Hydridotetrakis(triphenylphosphine)rhodium(I)
• Mol file: 25869-38-9.mol

Synonyms:Hydridotetrakis(triphenylphosphine)rhodium(I);18284-36-1;rhodium;triphenylphosphane;25869-38-9;Rhodium, tetrakis(triphenylphosphine)-;HRh(PPh3)4;DTXSID90475127;YCA46885;MFCD16876684;AKOS025310731;SC10382;Hydrido[tetrakis(triphenylphosphoranyl)]rhodium;D81947;HRH(PPH3)4;HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I);HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I);TETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM HYDRIDE;TETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE

Chemical Property of Hydridotetrakis(triphenylphosphine)rhodium(I)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 1151.27004
• Heavy Atom Count: 77
• Complexity: 202

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Rh]

Technology Process of Hydridotetrakis(triphenylphosphine)rhodium(I)

There total 3 articles about Hydridotetrakis(triphenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Wilkinson's catalyst (14694-95-2) + triphenylphosphine (603-35-0) → Rh(PPh3)4 (25869-38-9)

Guidance literature:

In toluene; acetonitrile; Electrochem. Process; electrochemical redn.; solvent: 85% CH3CN/15% toluene; in a soln. containing (Et4N)ClO4;

Reference yield:

Rh(PPh3)3(1+)*BF4(1-) (36656-65-2) → Rh(PPh3)4 (25869-38-9)

Guidance literature:

Multi-step reaction with 2 steps

1: further solvent(s)

2: toluene; acetonitrile

In toluene; acetonitrile;

Reference yield:

rhodium(III) chloride trihydrate + triphenylphosphine (603-35-0) → Rh(PPh3)4 (25869-38-9)

Guidance literature:

Electrochem. Process; electrochem. redn.;

upstream raw materials:

triphenylphosphine

Wilkinson's catalyst

Rh(PPh₃)3⁽¹⁺⁾*BF₄^(1-)

Downstream raw materials:

hydridotris(triphenylphosphine)rhodium