Cyclopropanecarboxylic acid, 3-(3-methoxy-2-meth

Base Information

Chemical Name:Cyclopropanecarboxylic acid, 3-(3-methoxy-2-meth
CAS No.:26074-74-8
Molecular Formula:C₁₂H₁₈O₄
Molecular Weight:226.273
Hs Code.:
DSSTox Substance ID:DTXSID10874355

Synonyms:SCHEMBL808887;DTXSID10874355;YYRMJZXCARUTDN-VOTSOKGWSA-N;CYCLOPROPANECARBOXYLIC ACID, 3-(3-METHOXY-2-METH;Methyl 3-[(1E)-3-methoxy-2-methyl-3-oxo-1-propenyl]-2,2-dimethylcyclopropanecarboxylate #;Cyclopropanecarboxylic acid, 3-(3-methoxy-2-methyl-3-oxo-1-propenyl)-2,2-dimethyl-, methyl ester, [1.alpha.,2.beta.(E)]-

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Chemical Property of Cyclopropanecarboxylic acid, 3-(3-methoxy-2-meth

Chemical Property:

XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:226.12050905
Heavy Atom Count:16
Complexity:341

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=CC1C(C1(C)C)C(=O)OC)C(=O)OC
Isomeric SMILES:C/C(=C\C1C(C1(C)C)C(=O)OC)/C(=O)OC

Technology Process of Cyclopropanecarboxylic acid, 3-(3-methoxy-2-meth

There total 19 articles about Cyclopropanecarboxylic acid, 3-(3-methoxy-2-meth which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 497-95-0,20053-54-7,22413-50-9,33383-55-0,40253-02-9,40253-03-0,54984-63-3,54984-64-4,55029-66-8,56390-95-5,56390-97-7,56390-98-8,72120-98-0,120294-50-0,120294-51-1
(+/-)-3t-(3t-carboxy-2,2-dimethyl-cycloprop-r-yl)-2-methyl-acrylic acid

: 22467-83-0,22467-87-4,26074-74-8,27335-44-0,41977-61-1,55821-14-2,67530-24-9,113829-78-0,113829-79-1
(+/-)-3t-(3t-methoxycarbonyl-2,2-dimethyl-cycloprop-r-yl)-2-methyl-acrylic acid methyl ester

Guidance literature:: DOI:10.1039/jr9630004957

Reference yield:

: 6227-47-0
3-(2-methoxycarbonyl-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid-(2-methyl-3-penta-2,4-dienyl-4-semicarbazono-cyclopent-2-enyl ester)

: 26074-74-8,41977-61-1,55821-14-2
3-(3-methoxycarbonyl-2,2-dimethyl-cyclopropyl)-2-methyl-acrylic acid methyl ester

: 497-96-1,717-56-6,26767-71-5,26771-02-8,26771-09-5,26771-22-2,29799-54-0,29799-55-1,29799-56-2,29799-57-3
3-(2-methoxycarbonyl-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid

Guidance literature:

Reference yield:

: 112753-41-0
5-(2-Hydroxy-2-methoxycarbonyl-propyl)-3,3-dimethyl-3H-pyrazole-4-carboxylic acid methyl ester

: 22467-83-0,22467-87-4,26074-74-8,27335-44-0,41977-61-1,55821-14-2,67530-24-9,113829-78-0,113829-79-1
(+/-)-3t-(3c-methoxycarbonyl-2,2-dimethyl-cycloprop-r-yl)-2-methyl-acrylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 60 percent / 2.) H₂ / 2.) PtO₂ / ethyl acetate / 0.33 h / Irradiation

2: CO₂CH₃NSO₂N(C₂H₅)3 / toluene / 0.67 h / 80 °C

With CO₂CH₃NSO₂N(C₂H₅)3; hydrogen; platinum(IV) oxide; In ethyl acetate; toluene;
DOI:10.1016/S0040-4020(01)90022-5