2-[([1,1'-Biphenyl]-2-yl)sulfanyl]aniline

Base Information

• Chemical Name: 2-[([1,1'-Biphenyl]-2-yl)sulfanyl]aniline
• CAS No.: 2688-98-4
• Molecular Formula: C18H15NS
• Molecular Weight: 277.39
• DSSTox Substance ID: DTXSID70548065
• Wikidata: Q82426655
• Mol file: 2688-98-4.mol

Synonyms:2688-98-4;2-[([1,1'-Biphenyl]-2-yl)sulfanyl]aniline;DTXSID70548065

Chemical Property of 2-[([1,1'-Biphenyl]-2-yl)sulfanyl]aniline

Chemical Property:

• XLogP3: 4.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 277.09252066
• Heavy Atom Count: 20
• Complexity: 287

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=CC=C2SC3=CC=CC=C3N

Technology Process of 2-[([1,1'-Biphenyl]-2-yl)sulfanyl]aniline

There total 6 articles about 2-[([1,1'-Biphenyl]-2-yl)sulfanyl]aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

2-Phenylbenzensulfenanilid (37692-10-7) → 1-phenyl-2-[(2-phenylphenyl)disulfanyl]benzene (19813-97-9) + 2-Amino-2'-phenyl-diphenylsulfid (2688-98-4) + 4-([1,1'-biphenyl]-2-ylthio)aniline (37692-13-0) + aniline (62-53-3)

Guidance literature:

In benzene; at 150 ℃; for 40h; Title compound not separated from byproducts;

Reference yield: 75.0%

2-Phenylbenzensulfenanilid (37692-10-7) → 1-phenyl-2-[(2-phenylphenyl)disulfanyl]benzene (19813-97-9) + 2-Amino-2'-phenyl-diphenylsulfid (2688-98-4) + 4'-(biphenyl-2-ylthio)biphenyl-2-sulphenanilide (110228-53-0) + aniline (62-53-3)

Guidance literature:

In benzene; at 85 ℃; for 480h;

Reference yield:

2-Nitro-2'-phenyl-diphenylsulfid (2688-97-3) → 2-Amino-2'-phenyl-diphenylsulfid (2688-98-4)

Guidance literature:

With iron; acetic acid;

DOI:10.1016/S0040-4020(01)98289-4

upstream raw materials:

2-Phenylbenzensulfenanilid

2-Nitro-2'-phenyl-diphenylsulfid

2-phenylbenzenethiol

2-Chloronitrobenzene

Downstream raw materials:

2'-Phenyl-2-chlorsulfonyl-diphenylsulfid