Benzene, [(1-bromoethyl)sulfinyl]-

Base Information

• Chemical Name: Benzene, [(1-bromoethyl)sulfinyl]-
• CAS No.: 26910-34-9
• Molecular Formula: C8H9BrOS
• Molecular Weight: 233.129
• DSSTox Substance ID: DTXSID50458759
• Nikkaji Number: J1.915.754G
• Mol file: 26910-34-9.mol

Synonyms:Benzene, [(1-bromoethyl)sulfinyl]-;26910-34-9;(1-Bromoethyl)phenyl sulfoxide;(1-bromoethyl) phenyl sulfoxide;SCHEMBL11760283;DTXSID50458759;RWWLZQMVOFBBRG-UHFFFAOYSA-N

Chemical Property of Benzene, [(1-bromoethyl)sulfinyl]-

Chemical Property:

• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 231.95575
• Heavy Atom Count: 11
• Complexity: 143

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(S(=O)C1=CC=CC=C1)Br

Technology Process of Benzene, [(1-bromoethyl)sulfinyl]-

There total 2 articles about Benzene, [(1-bromoethyl)sulfinyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

ethylphenylsulfoxide (51207-25-1,67529-33-3,104113-36-2,4170-80-3) → α-Bromoethyl phenyl sulfoxide (26910-34-9)

Guidance literature:

With N-Bromosuccinimide; silica gel; for 30h; Ambient temperature;

DOI:10.1055/s-1986-31793

Reference yield:

→ α-Bromoethyl phenyl sulfoxide (26910-34-9)

Guidance literature:

entspr. Sulfoxid, NBS (CCl4 od. CH2Cl2);

Reference yield: 77.0%

α-Bromoethyl phenyl sulfoxide (26910-34-9) → phenyl α-bromovinyl sulfide (80485-53-6)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; triethylamine; In diethyl ether; at 0 ℃; for 0.5h;

upstream raw materials:

ethylphenylsulfoxide

Downstream raw materials:

ethylphenylsulfoxide

1,3-bis(phenylsulfinyl)butane

phenyl α-bromovinyl sulfide

2-methoxyethyl phenyl sulfoxide