Benzoic acid, 3,5-dinitro-, 4-methylphenyl ester

Base Information

• Chemical Name: Benzoic acid, 3,5-dinitro-, 4-methylphenyl ester
• CAS No.: 27563-96-8
• Molecular Formula: C14H10N2O6
• Molecular Weight: 302.243
• Mol file: 27563-96-8.mol

Synonyms:p-methylphenyl 3,5-dinitrobenzoate;p-Tolyl-(3.5-dinitro-benzoat);3,5-Dinitro-benzoesaeure-p-tolylester;3,5-dinitro-benzoic acid p-tolyl ester;4-methylphenyl 3,5-dinitrobenzoate;

Chemical Property of Benzoic acid, 3,5-dinitro-, 4-methylphenyl ester

Chemical Property:

• PSA: 117.94000
• LogP: 4.07700

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 3,5-dinitro-, 4-methylphenyl ester

There total 2 articles about Benzoic acid, 3,5-dinitro-, 4-methylphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

p-cresol (106-44-5) + 3,5-dinitrobenoyl chloride (99-33-2) → 3,5-dinitrobenzoate of 4-methylphenol (27563-96-8)

Guidance literature:

With pyridine; In tetrahydrofuran; for 0.333333h; Heating;

DOI:10.3987/com-01-9242

Reference yield:

→ 3,5-dinitrobenzoate of 4-methylphenol (27563-96-8)

Guidance literature:

/BRN= 2299061/;

Reference yield: 86.0%

3,5-dinitrobenzoate of 4-methylphenol (27563-96-8) → 3,5-diamino-benzoic acid p-tolyl ester (367970-21-6)

Guidance literature:

With hydrogen; palladium on activated charcoal; In tetrahydrofuran; at 20 ℃; under 760 Torr;

DOI:10.3987/com-01-9242

upstream raw materials:

p-cresol

3,5-dinitrobenoyl chloride

Downstream raw materials:

3,5-diamino-benzoic acid p-tolyl ester

p-cresolate

3,5-dinitrobenzoic acid

C₇₈H₈₂N₂O₁₄Si₄

Refernces

• 1、 Feldman, Ken S.,Liu, Yanze,Saunders, Joe C.,Masters, Katherine M.,Campbell, Robert F.. "Heterocycles in organic materials chemistry. Synthesis of di-, tri-, and tetraimide polycarboxylic acids for use in organic network assembly". . p. 1527 - 1554. Retrieved 2007/10/03.