2,7-Diiodo-9,9-dioctyl-9H-fluorene

Base Information

Chemical Name:2,7-Diiodo-9,9-dioctyl-9H-fluorene
CAS No.:278176-06-0
Molecular Formula:C29H40I2
Molecular Weight:642.43700
Hs Code.:2903999090
DSSTox Substance ID:DTXSID00403411
Nikkaji Number:J1.960.143I
Mol file:278176-06-0.mol

Synonyms:2,7-Diiodo-9,9-dioctyl-9H-fluorene;278176-06-0;2,7-diiodo-9,9-dioctylfluorene;9H-Fluorene, 2,7-diiodo-9,9-dioctyl-;2 7-Diiodo-9 9-dioctyl-9H-fluorene 97;SCHEMBL1923234;DTXSID00403411;2, 7-diiodo-9, 9-dioctylfluorene;MFCD03094033;AKOS015912766;2,7-Diiodo-9,9-dioctyl-9H-fluorene, 96%

Suppliers and Price of 2,7-Diiodo-9,9-dioctyl-9H-fluorene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
2,7-Diiodo-9,9-dioctyl-9H-fluorene 96%
500mg
$ 163.00

American Custom Chemicals Corporation
2,7-DIIODO-9,9-DIOCTYL-9H-FLUORENE 95.00%
5MG
$ 503.02

AK Scientific
2,7-Diiodo-9,9-dioctyl-9H-fluorene
500mg
$ 265.00

Total 5 raw suppliers

Chemical Property of 2,7-Diiodo-9,9-dioctyl-9H-fluorene

Chemical Property:

Melting Point:55-57oC(lit.)
PSA：0.00000
LogP:10.66350
XLogP3:13.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:14
Exact Mass:642.12195
Heavy Atom Count:31
Complexity:445

Purity/Quality:

97% ^*data from raw suppliers

2,7-Diiodo-9,9-dioctyl-9H-fluorene 96% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCCC1(C2=C(C=CC(=C2)I)C3=C1C=C(C=C3)I)CCCCCCCC

Technology Process of 2,7-Diiodo-9,9-dioctyl-9H-fluorene

There total 4 articles about 2,7-Diiodo-9,9-dioctyl-9H-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 111-83-1
1-bromo-octane

: 16218-28-3
2,7-diiodofluorene

: 278176-06-0
2,7-diiodo-9,9-dioctyl-9H-fluorene

Guidance literature:: With potassium tert-butylate; In N,N-dimethyl-formamide; at 20 - 40 ℃; for 0.583333h; Inert atmosphere;
DOI:10.1002/chem.201000236

Reference yield: 60.0%

: 123863-99-0
9,9-dioctyl-9H-fluorene

: 278176-06-0
2,7-diiodo-9,9-dioctyl-9H-fluorene

Guidance literature:: With potassium iodate; sulfuric acid; iodine; acetic acid; In tetrachloromethane; water; at 80 ℃; for 48h;
DOI:10.1021/ma2025144

Reference yield:

: 86-73-7
9H-fluorene

: 278176-06-0
2,7-diiodo-9,9-dioctyl-9H-fluorene

Guidance literature:: Multi-step reaction with 2 steps

1: iodine; iodic acid / water; ethanol / 60 °C

2: sodium hydroxide; tetrabutylammomium bromide

With tetrabutylammomium bromide; iodine; iodic acid; sodium hydroxide; In ethanol; water;
DOI:10.1039/c3tc32029d