Palladium;tris(4-methylphenyl)phosphane

Base Information

Chemical Name:Palladium;tris(4-methylphenyl)phosphane
CAS No.:27903-26-0
Molecular Formula:C63H63P3Pd
Molecular Weight:1019.53
Hs Code.:
DSSTox Substance ID:DTXSID10537716
Mol file:27903-26-0.mol

Synonyms:27903-26-0;DTXSID10537716;Palladium--tris(4-methylphenyl)phosphane (1/3)

Suppliers and Price of Palladium;tris(4-methylphenyl)phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Palladium;tris(4-methylphenyl)phosphane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:9
Exact Mass:1018.31774
Heavy Atom Count:67
Complexity:263

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=C(C=C3)C.CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=C(C=C3)C.CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=C(C=C3)C.[Pd]

Technology Process of Palladium;tris(4-methylphenyl)phosphane

There total 1 articles about Palladium;tris(4-methylphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (2-methylallyl)palladium-chloride dimer

: 1038-95-5,218281-19-7
Tri(p-tolyl)phosphine

: 27903-26-0
[Pd{P(p-tol)₃}₃]

Guidance literature:: In methanol; at 20 ℃; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.inorgchem.1c00631

Reference yield: 70.0%

: 27903-26-0
[Pd{P(p-tol)₃}₃]

: 71353-67-8
pent-3-ynyl chloroformate

: (CH₃CCCH₂CH₂OCO)Pd(P(C₆H₄CH₃)3)2Cl

Guidance literature:: In toluene; chloroformate (10-25% excess) was added dropwise over 1 min under N2 to a stirred toluene soln. of Pd-complex at 60°C, mixt. was heated for 75 min; recrystd. from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/ja00331a019

Reference yield: 61.0%

: 27903-26-0
[Pd{P(p-tol)₃}₃]

: 80937-33-3
oxygen

: 83618-03-5
Pd(O₂)(P(p-tolyl)3)2

Guidance literature:: In diethyl ether; O2 was bubbled to suspn. Pd complex in Et2O; ppt. was collected, washed with Et2O, dried under reduced pressure; elem. anal.;
DOI:10.1021/ja071744g