Phenanthro(3,4-b)oxirene, 1a,2,3,9c-tetrahydro-

Base Information

Chemical Name:Phenanthro(3,4-b)oxirene, 1a,2,3,9c-tetrahydro-
CAS No.:66997-69-1
Molecular Formula:C14H12O
Molecular Weight:196.26
Hs Code.:

Synonyms:tetrahydrophenanthrene-3,4-epoxide;1,2,3,4-tetrahydrophenanthrene-3,4-oxide;1a,2,3,9c-Tetrahydro-1-oxa-cyclopropa[c]phenanthrene;

Suppliers and Price of Phenanthro(3,4-b)oxirene, 1a,2,3,9c-tetrahydro-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Phenanthro(3,4-b)oxirene, 1a,2,3,9c-tetrahydro-

Chemical Property:

Vapor Pressure:3.84E-05mmHg at 25°C
Refractive Index:1.5385 (estimate)
Boiling Point:363.2°Cat760mmHg
Flash Point:166.9°C
PSA：12.53000
Density:1.225g/cm³
LogP:3.22590

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Phenanthro(3,4-b)oxirene, 1a,2,3,9c-tetrahydro-

There total 1 articles about Phenanthro(3,4-b)oxirene, 1a,2,3,9c-tetrahydro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 313511-71-6
3-bromo-1,2,3,4-tetrahydro-4-hydroxyphenanthrene

: 66997-69-1
1,2,3,4-tetrahydrophenanthrene 3,4-oxide

Guidance literature:: With sodium carbonate; In tetrahydrofuran; water; at 20 ℃; for 48h;
DOI:10.1021/jo000086e

Reference yield:

: 66997-69-1
1,2,3,4-tetrahydrophenanthrene 3,4-oxide

: 135560-89-3,135636-93-0
(3S,4S)-N₆-(4-(3-acetoxy-1,2,3,4-tetrahydrophenanthrenyl))-5'-(9-phenylxanthen-9-yl)-2'-deoxyadenosine

Guidance literature:: Multi-step reaction with 5 steps

1: 78 percent / NH₃ / 16 h / 100 °C

2: 40 mg / pyridine, hexamethyldisilazane / dimethylformamide / 24 h / 65 °C

3: 95 percent / 4-(N,N-dimethylamino)pyridine, pyridine / 24 h

4: 96 percent / n-Bu₄N⁺F^- / tetrahydrofuran / 1 h / Ambient temperature

5: 56 percent / pyridine / 1 h

With pyridine; dmap; tetrabutyl ammonium fluoride; ammonia; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; N,N-dimethyl-formamide;

Reference yield:

: 66997-69-1
1,2,3,4-tetrahydrophenanthrene 3,4-oxide

: 135560-89-3,135636-93-0
(3R,4R)-N₆-(4-(3-acetoxy-1,2,3,4-tetrahydrophenanthrenyl))-5'-(9-phenylxanthen-9-yl)-2'-deoxyadenosine

Guidance literature:: Multi-step reaction with 5 steps

1: 78 percent / NH₃ / 16 h / 100 °C

2: 40 mg / pyridine, hexamethyldisilazane / dimethylformamide / 24 h / 65 °C

3: 79 percent / 4-(N,N-dimethylamino)pyridine, pyridine / 24 h

4: 88 percent / n-Bu₄N⁺F^- / tetrahydrofuran / 1 h / Ambient temperature

5: 48 percent / pyridine / 0.75 h

With pyridine; dmap; tetrabutyl ammonium fluoride; ammonia; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; N,N-dimethyl-formamide;