2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4a-methyl-, cis-

Base Information

Chemical Name:2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4a-methyl-, cis-
CAS No.:31654-83-8
Molecular Formula:C11H18O
Molecular Weight:
Hs Code.:
DSSTox Substance ID:DTXSID50443943
Nikkaji Number:J2.461.137J
Wikidata:Q82261939
Mol file:31654-83-8.mol

Synonyms:DTXSID50443943;2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4a-methyl-, cis-;31654-83-8;(2S)-4abeta-Methyl-2,3,4,4a,5,6,7,8-octahydronaphthalene-2beta-ol;InChI=1/C11H18O/c1-11-6-3-2-4-9(11)8-10(12)5-7-11/h8,10,12H,2-7H2,1H3/t10-,11-/m0/s

Suppliers and Price of 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4a-methyl-, cis-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4a-methyl-, cis-

Chemical Property:

XLogP3:2.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:166.135765193
Heavy Atom Count:12
Complexity:207

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC12CCCCC1=CC(CC2)O
Isomeric SMILES:C[C@@]12CCCCC1=C[C@H](CC2)O

Technology Process of 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4a-methyl-, cis-

There total 4 articles about 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4a-methyl-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 826-56-2
4a-methyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one

: 2547-28-6
2-Hydroxy-10-methyldecalin

: 31654-83-8,40447-83-4,83606-04-6,83606-05-7,83648-94-6,26675-10-5
(+/-)-cis-4a-methyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2-ol

: 83606-05-7
(+/-)-trans-4a-methyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2-ol

Guidance literature:: With sodium tetrahydroborate; tetrabutylammomium bromide; sodium sulfate; In water; toluene; at 50 ℃; for 2h; Yield given;
DOI:10.1016/0040-4020(82)85020-5

Reference yield:

: 83606-06-8,83606-07-9
Benzoic acid 4a-methyl-2,3,4,4a,5,6,7,8-octahydro-naphthalen-2-yl ester

: 31654-83-8,40447-83-4,83606-04-6,83606-05-7,83648-94-6,26675-10-5
(+/-)-cis-4a-methyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2-ol

: 83606-05-7
(+/-)-trans-4a-methyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2-ol

Guidance literature:: With potassium hydroxide; In methanol; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Heating;
DOI:10.1021/ja00390a008

Reference yield:

: 22789-80-6
4a-methyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-one

: 31654-83-8,40447-83-4,83606-04-6,83606-05-7,83648-94-6,26675-10-5
(+/-)-cis-4a-methyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / tBuOK / 2-methyl-propan-2-ol

2: 1.) L-Selectride, 2.) NaOH, H₂O₂ / 1.) -Et₂O, 78 deg C, 3 h and warmed to room temperature, 1 h, 2.) H₂O, 2 h.

With sodium hydroxide; potassium tert-butylate; dihydrogen peroxide; L-Selectride; In tert-butyl alcohol;
DOI:10.1016/S0040-4020(98)83052-4