cis-4-Hydroxymellein

Base Information

Chemical Name:cis-4-Hydroxymellein
CAS No.:32885-83-9
Molecular Formula:C10H10O4
Molecular Weight:
Hs Code.:
UNII:YJ8535DF71
Nikkaji Number:J2.496.539B
Wikidata:Q27294545
ChEMBL ID:CHEMBL444818

Synonyms:cis-4-Hydroxymellein;4-Hydroxymellein, cis-;cis-4-Hydroxymellein, (-)-;(3R,4R)-cis-4-Hydroxymellein;cis-(3R,4R)-4-Hydroxymellein;YJ8535DF71;UNII-YJ8535DF71;Isocoumarin, 3,4-dihydro-4,8-dihydroxy-3-methyl-, cis-;1H-2-Benzopyran-1-one, 3,4-dihydro-4,8-dihydroxy-3-methyl-, (3R,4R)-;1H-2-Benzopyran-1-one, 3,4-dihydro-4,8-dihydroxy-3-methyl-, (3R-cis)-;32885-83-9;(3R,4R)-hydroxymellein;CHEMBL444818;Q27294545

Suppliers and Price of cis-4-Hydroxymellein

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of cis-4-Hydroxymellein

Chemical Property:

XLogP3:1.3
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:194.05790880
Heavy Atom Count:14
Complexity:240

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1C(C2=C(C(=CC=C2)O)C(=O)O1)O
Isomeric SMILES:C[C@@H]1[C@@H](C2=C(C(=CC=C2)O)C(=O)O1)O

Technology Process of cis-4-Hydroxymellein

There total 8 articles about cis-4-Hydroxymellein which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: C₁₅H₁₇NO₆

: 32885-83-9,33788-22-6,60132-20-9,70287-70-6
4-hydroxymellein

Guidance literature:: C₁₅H₁₇NO₆; With potassium carbonate; In methanol; water; at 20 ℃; for 17h;

With hydrogenchloride; In methanol; water; for 2h;
DOI:10.1021/ol502225p

Reference yield: 86.0%

: C₁₅H₁₇NO₆

: 32885-83-9,33788-22-6,60132-20-9,70287-70-6
cis-4-hydroxymellein

Guidance literature:: C₁₅H₁₇NO₆; With potassium carbonate; In methanol; water; at 20 ℃; for 17h;

With hydrogenchloride; In methanol; water; for 2h;
DOI:10.1021/ol502225p

Reference yield: 61.0%

: 1360789-38-3
methyl 2-acetoxy-6-((E)-prop-1-enyl)benzoate

: 32885-83-9,33788-22-6,60132-20-9,70287-70-6
(3S,4S)-4-hydroxymellein

Guidance literature:: methyl 2-acetoxy-6-((E)-prop-1-enyl)benzoate; With (R)-methyl 2-(2-(diacetoxyiodo)phenoxy)-3-methylbutanoate; boron trifluoride diethyl etherate; acetic acid; In dichloromethane; at -80 - -40 ℃; for 2h;

With sodium hydroxide; In methanol; water; at 0 ℃; for 0.166667h; Saturated solution;

With hydrogenchloride; In methanol; water; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/ol300185u