Technology Process of Methanone, [4-(4-bromobutoxy)phenyl](4-hydroxyphenyl)-
There total 1 articles about Methanone, [4-(4-bromobutoxy)phenyl](4-hydroxyphenyl)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
4,4'-Dihydroxybenzophenone;
With
potassium hydride;
In
tetrahydrofuran; N,N-dimethyl-formamide;
1,4-dibromo-butane;
In
tetrahydrofuran; N,N-dimethyl-formamide;
Further stages.;
DOI:10.1039/b009553m
- Guidance literature:
-
With
titanium tetrachloride; zinc;
In
tetrahydrofuran;
TiCl4 mixed with Zn at o°C, refluxed for 2 h, cooled to room temp., mixed with Re complex and benzophenone, refluxed for 2 h, cooled to room temp.; stirred with H2O and CH2Cl2, MAS;
DOI:10.1039/b009553m
- Guidance literature:
-
With
titanium tetrachloride; zinc;
In
tetrahydrofuran;
under Ar; TiCl4 was added dropwise to a suspn. of Zn in THF at -10°C, mixt. was heated at reflux for 1.5 h, allowed to cool to room temp., ketone and complex were added dropwise, mixt. was heated for 2 h, cooled to room temp.; hydrolyzed with 10% K2CO3, extd. with ether, solvent was removed, chromy. (silica gel, Et2O/pentane);
DOI:10.1016/S0022-328X(01)00953-6
