Pyrrolidine, 1-phenyl-2-phenylimino-

Base Information

• Chemical Name: Pyrrolidine, 1-phenyl-2-phenylimino-
• CAS No.: 7561-79-7
• Molecular Formula: C16H16N2
• Molecular Weight: 236.316
• Nikkaji Number: J3.513.198A
• Mol file: 7561-79-7.mol

Synonyms:Pyrrolidine, 1-phenyl-2-phenylimino-;SCHEMBL10463862;SCHEMBL10463864;Pyrrolidine, 1-phenyl-2-phenylimino-,;7561-79-7

Chemical Property of Pyrrolidine, 1-phenyl-2-phenylimino-

Chemical Property:

• Vapor Pressure: 1.34E-05mmHg at 25°C
• Boiling Point: 367.8°Cat760mmHg
• Flash Point: 176.2°C
• Density: 1.07g/cm³
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 236.131348519
• Heavy Atom Count: 18
• Complexity: 286

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC(=NC2=CC=CC=C2)N(C1)C3=CC=CC=C3

Technology Process of Pyrrolidine, 1-phenyl-2-phenylimino-

There total 3 articles about Pyrrolidine, 1-phenyl-2-phenylimino- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1-phenylpyrrolidin-2-imine hydrobromide + 2-(trimethylsilyl)phenyl trifluoromethanesulfonate (88284-48-4) → N,N'-diphenylpyrrolidin-2-imine (7561-79-7)

Guidance literature:

1-phenylpyrrolidin-2-imine hydrobromide; With sodium hydrogencarbonate; cesium fluoride; In acetonitrile; at 20 ℃; for 0.0833333h;

2-(trimethylsilyl)phenyl trifluoromethanesulfonate; In acetonitrile; at 20 ℃; for 10h; Concentration;

DOI:10.1016/j.tetlet.2015.06.017

Reference yield:

aniline (62-53-3) → N,N'-diphenylpyrrolidin-2-imine (7561-79-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: butan-1-ol / 6 h / 100 - 115 °C

2.1: cesium fluoride; sodium hydrogencarbonate / acetonitrile / 0.08 h / 20 °C

2.2: 10 h / 20 °C

With sodium hydrogencarbonate; cesium fluoride; In acetonitrile; butan-1-ol;

DOI:10.1016/j.tetlet.2015.06.017

Reference yield:

→ N,N'-diphenylpyrrolidin-2-imine (7561-79-7)

Guidance literature:

1-Phenyl-2-imino-pyrrolidin, Anilin, Siedetemp.;

DOI:10.1021/jo01278a052

upstream raw materials:

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

aniline