Phenol, 4,4'-methylenebis[2-[[[(1R,2R)-2-[[[3,5-bis(1,1-dimethylethyl)-2-hydroxy phenyl]methylene]amino]cyclohexyl]imino]methyl]-6-(1,1-dimethylethyl)-

Base Information

• Chemical Name: Phenol, 4,4'-methylenebis[2-[[[(1R,2R)-2-[[[3,5-bis(1,1-dimethylethyl)-2-hydroxy phenyl]methylene]amino]cyclohexyl]imino]methyl]-6-(1,1-dimethylethyl)-
• CAS No.: 350047-60-8
• Molecular Formula: C65H92N4O4
• Molecular Weight: 993.47
• Mol file: 350047-60-8.mol

Synonyms:

Chemical Property of Phenol, 4,4'-methylenebis[2-[[[(1R,2R)-2-[[[3,5-bis(1,1-dimethylethyl)-2-hydroxy phenyl]methylene]amino]cyclohexyl]imino]methyl]-6-(1,1-dimethylethyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenol, 4,4'-methylenebis[2-[[[(1R,2R)-2-[[[3,5-bis(1,1-dimethylethyl)-2-hydroxy phenyl]methylene]amino]cyclohexyl]imino]methyl]-6-(1,1-dimethylethyl)-

There total 5 articles about Phenol, 4,4'-methylenebis[2-[[[(1R,2R)-2-[[[3,5-bis(1,1-dimethylethyl)-2-hydroxy phenyl]methylene]amino]cyclohexyl]imino]methyl]-6-(1,1-dimethylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

5,5'-methylene bis(3-tert-butyl)-2-hydroxybenzaldehyde (199190-77-7) + N-(2-hydroxy-3,5-di-tert-butyl benzaldehyde)-1-amino-2-cyclohexeneimine → 5,5-methylene di[(R,R)-{N-(3-tert-butyl salicylidine)-N'-(3',5'-di-tert-butyl salicylidene)}-1,2-cyclohexanediamine] (350047-60-8)

Guidance literature:

In ethanol; dichloromethane; for 8h; Heating;

DOI:10.1016/S0957-4166(01)00057-X

Reference yield:

3-tert-butyl-2-hydroxybenzaldehyde (24623-65-2) → 5,5-methylene di[(R,R)-{N-(3-tert-butyl salicylidine)-N'-(3',5'-di-tert-butyl salicylidene)}-1,2-cyclohexanediamine] (350047-60-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 70 percent / AcOH; H₂SO₄ / 24 h / 90 °C

2: 85 percent / CH₂Cl₂; ethanol / 8 h / Heating

With sulfuric acid; acetic acid; In ethanol; dichloromethane;

DOI:10.1016/S0957-4166(01)00057-X

Reference yield:

3,5-di-tert-butyl-2-hydroxybenzaldehyde (37942-07-7) → 5,5-methylene di[(R,R)-{N-(3-tert-butyl salicylidine)-N'-(3',5'-di-tert-butyl salicylidene)}-1,2-cyclohexanediamine] (350047-60-8)

Guidance literature:

Multi-step reaction with 2 steps

1: CHCl₃ / 48 h / 0 °C

2: 85 percent / CH₂Cl₂; ethanol / 8 h / Heating

In ethanol; dichloromethane; chloroform;

DOI:10.1016/S0957-4166(01)00057-X

upstream raw materials:

5,5'-methylene bis(3-tert-butyl)-2-hydroxybenzaldehyde

3,5-di-tert-butyl-2-hydroxybenzaldehyde

3-tert-butyl-2-hydroxybenzaldehyde

(1R,2R)-1,2-diaminocyclohexane