Carbonochloridic acid, 2,3-dimethylphenyl ester

Base Information

• Chemical Name: Carbonochloridic acid, 2,3-dimethylphenyl ester
• CAS No.: 36018-19-6
• Molecular Formula: C9H9ClO2
• Molecular Weight: 184.622
• Mol file: 36018-19-6.mol

Synonyms:2,3-Dimethylphenyl-chlorameisensaeureester;2,3-Dimethylphenylchloroformate;

Chemical Property of Carbonochloridic acid, 2,3-dimethylphenyl ester

Chemical Property:

• Boiling Point: 94 °C(Press: 12 Torr)
• PSA: 26.30000
• Density: 1.195±0.06 g/cm3(Predicted)
• LogP: 3.04100

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbonochloridic acid, 2,3-dimethylphenyl ester

There total 2 articles about Carbonochloridic acid, 2,3-dimethylphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(trichloromethyl) carbonate (32315-10-9) + 2,3-Dimethylphenol (526-75-0) → 2,3-dimethylphenyl chloroformate (36018-19-6)

Guidance literature:

With N,N-diethylaniline; In toluene; at 20 ℃; for 2h; Cooling with ice;

DOI:10.1021/acs.orglett.8b01980

Reference yield:

→ 2,3-dimethylphenyl chloroformate (36018-19-6)

Guidance literature:

Reference yield: 76.0%

2,3-dimethylphenyl chloroformate (36018-19-6) → 3-fluoro-o-xylene (443-82-3)

Guidance literature:

With hydrogen fluoride; In various solvent(s); at 150 ℃; for 6h; under 19501.6 Torr;

DOI:10.1021/jo9716486

upstream raw materials:

bis(trichloromethyl) carbonate

2,3-Dimethylphenol

Downstream raw materials:

α,α'-Dichloro-2,3-xylylchloroformiat

3-fluoro-o-xylene

3-chloro-o-xylene

α,α'-Dichloro-2,3-xylyl-carbamat