1,2-diethylcyclohexane

Base Information

• Chemical Name: 1,2-diethylcyclohexane
• CAS No.: 3642-13-5
• Molecular Formula: C₁₀H₂₀
• Molecular Weight: 140.269
• Mol file: 3642-13-5.mol

Synonyms:1,2-Diaethyl-cyclohexan;1,2-Diaethyl-4-methyl-benzol;Benzene,1,2-diethyl-4-methyl;1,2-diethyl-cyclohexane;1,2-diethyl-4-methyl-benzene;3,4-Diethyl-1-methylbenzol;3,4-diethyltoluene;1-methyl-3,4-diethylbenzene;1,2-Diethyl-cyclohexan;

Chemical Property of 1,2-diethylcyclohexane

Chemical Property:

• Vapor Pressure: 1.63mmHg at 25°C
• Boiling Point: 174.3oC at 760 mmHg
• Flash Point: 47.8oC
• PSA: 0.00000
• Density: 0.772g/cm3
• LogP: 3.61280

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-diethylcyclohexane

There total 23 articles about 1,2-diethylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

ortho-diethylbenzene (253185-02-3,135-01-3) → cis-1,2-diethylcyclohexane (824-43-1) + trans-N,N'-dimethyl-1,2-cyclohexanediamine (824-43-1,3642-13-5,13990-95-9)

Guidance literature:

With hydrogen; platinum; In acetic acid; for 10h; under 2250.2 Torr; Product distribution;

Reference yield: 36.0%

dispiro<2.0.2.4.>dec-8-ene (24029-73-0) → cis-1,2-diethylcyclohexane (824-43-1) + ortho-diethylbenzene (253185-02-3,135-01-3) + Dispiro<2.0.2.4>decan (24029-74-1) + 1,2-Diethyl-1-cyclohexen (103394-01-0) + trans-N,N'-dimethyl-1,2-cyclohexanediamine (824-43-1,3642-13-5,13990-95-9)

Guidance literature:

With hydrogen; palladium on activated charcoal; In methanol; Product distribution; Mechanism; Ambient temperature;

Reference yield:

decalin (91-17-8) → 1-phenyl-2-methylpropane (538-93-2) + 1,1,3,5-tetramethylcyclohexane (4306-65-4) + 1,2-diethylcyclohexane (3642-13-5,824-43-1,13990-95-9) + 1-methyl-2-propyl-cyclohexane (4291-79-6,4926-71-0,42806-77-9,130365-42-3,130365-43-4,130365-46-7,130365-47-8,130365-50-3,130365-51-4)

Guidance literature:

With 1.0%Pt-1.0%Ir/TiO2; hydrogen; at 350 ℃; for 6h; under 22502.3 Torr; Reagent/catalyst; Temperature; Catalytic behavior; Autoclave;

DOI:10.1016/j.apcata.2012.12.015

upstream raw materials:

1,2-dibromocyclohexane

diethylzinc

ortho-diethylbenzene

1,2-diethyl-cyclohexanol

Refernces

• 1、 Moraes, Rodrigo,Thomas, Karine,Thomas, Sebastien,Van Donk, Sander,Grasso, Giacomo,Gilson, Jean-Pierre,Houalla, Marwan. "Ring opening of decalin and methylcyclohexane over bifunctional Ir/WO 3/Al2O3 catalysts". . p. 30 - 43. Retrieved 2013/04/10.
• 2、 Haas, Andreas,Rabl, Sandra,Ferrari, Marco,Calemma, Vincenzo,Weitkamp, Jens. "Ring opening of decalin via hydrogenolysis on Ir/- and Pt/silica catalysts". experimental part. p. 97 - 109. Retrieved 2012/07/13.