Benzoic acid, 2-[(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxyphenyl)methoxy]-1-nonenyl]- 6-methoxy-

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Chemical Name:Benzoic acid, 2-[(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxyphenyl)methoxy]-1-nonenyl]- 6-methoxy-
CAS No.:366800-13-7
Molecular Formula:C25H32O7
Molecular Weight:444.525
Hs Code.:

Synonyms:

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Chemical Property of Benzoic acid, 2-[(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxyphenyl)methoxy]-1-nonenyl]- 6-methoxy-

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Technology Process of Benzoic acid, 2-[(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxyphenyl)methoxy]-1-nonenyl]- 6-methoxy-

There total 11 articles about Benzoic acid, 2-[(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxyphenyl)methoxy]-1-nonenyl]- 6-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 366800-16-0
methyl 2-{(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxybenzyl)oxy]non-1-enyl}-6-methoxybenzoate

: 366800-13-7
2-{(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxybenzyl)oxy]non-1-enyl}-6-methoxybenzoic acid

Guidance literature:: With lithium hydroxide; In tetrahydrofuran; methanol; at 75 ℃; for 76h;
DOI:10.1055/s-2001-16056

Reference yield:

: 79439-15-9
methyl trans-2-nonen-8-ynoate

: 366800-13-7
2-{(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxybenzyl)oxy]non-1-enyl}-6-methoxybenzoic acid

Guidance literature:: Multi-step reaction with 7 steps

1.1: 99 percent / DIBAH / CH₂Cl₂ / 23 °C

2.1: NaH / dimethylformamide / 3 h / 23 °C

2.2: 95 percent / dimethylformamide / 13 h / 0 - 23 °C

3.1: (DHQ)2PHAL; MeSO₂NH₂; K₂CO₃ / K₃Fe(CN)6; K₂OsO₄*2H₂O / 2-methyl-propan-2-ol; H₂O / 24 h / 0 °C

4.1: 94 percent / TsOH / tetrahydrofuran / 16 h / 23 °C

5.1: AIBN; Bu₃SnH / toluene / 16 h / 100 °C

5.2: 0.45 g / 2,6-di-tert-butyl-4-methylphenol; LiCl / [Pd(PPh₃)2Cl₂] / dimethylformamide / 48 h / 100 °C

6.1: 90 percent / aq. AcOH / 18 h / 23 °C

7.1: 87 percent / LiOH / methanol; tetrahydrofuran; H₂O / 76 h / 75 °C

With lithium hydroxide; Hydroquinone 1,4-phthalazinediyl diether; 2,2'-azobis(isobutyronitrile); methanesulfonamide; tri-n-butyl-tin hydride; sodium hydride; diisobutylaluminium hydride; potassium carbonate; toluene-4-sulfonic acid; acetic acid; potassium osmate(VI); potassium hexacyanoferrate(III); In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; 3.1: Sharpless asymmetric dihydroxylation / 5.2: Stille coupling;

Reference yield:

: 173043-70-4
(E)-2-nonen-8-yn-1-ol

: 366800-13-7
2-{(1E,7S,8S)-7,8-dihydroxy-9-[(4-methoxybenzyl)oxy]non-1-enyl}-6-methoxybenzoic acid

Guidance literature:: Multi-step reaction with 6 steps

1.1: NaH / dimethylformamide / 3 h / 23 °C

1.2: 95 percent / dimethylformamide / 13 h / 0 - 23 °C

2.1: (DHQ)2PHAL; MeSO₂NH₂; K₂CO₃ / K₃Fe(CN)6; K₂OsO₄*2H₂O / 2-methyl-propan-2-ol; H₂O / 24 h / 0 °C

3.1: 94 percent / TsOH / tetrahydrofuran / 16 h / 23 °C

4.1: AIBN; Bu₃SnH / toluene / 16 h / 100 °C

4.2: 0.45 g / 2,6-di-tert-butyl-4-methylphenol; LiCl / [Pd(PPh₃)2Cl₂] / dimethylformamide / 48 h / 100 °C

5.1: 90 percent / aq. AcOH / 18 h / 23 °C

6.1: 87 percent / LiOH / methanol; tetrahydrofuran; H₂O / 76 h / 75 °C

With lithium hydroxide; Hydroquinone 1,4-phthalazinediyl diether; 2,2'-azobis(isobutyronitrile); methanesulfonamide; tri-n-butyl-tin hydride; sodium hydride; potassium carbonate; toluene-4-sulfonic acid; acetic acid; potassium osmate(VI); potassium hexacyanoferrate(III); In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; 2.1: Sharpless asymmetric dihydroxylation / 4.2: Stille coupling;