1,2-Dihydro-1-thioxo-3H-pyrrolo[1,2-c]imidazol-3-one

Base Information

Chemical Name:1,2-Dihydro-1-thioxo-3H-pyrrolo[1,2-c]imidazol-3-one
CAS No.:37488-53-2
Molecular Formula:C₆H₄N₂OS
Molecular Weight:152.177
Hs Code.:
DSSTox Substance ID:DTXSID80393200
Nikkaji Number:J227.627E
Mol file:37488-53-2.mol

Synonyms:37488-53-2;1,2-Dihydro-1-thioxo-3H-pyrrolo[1,2-c]imidazol-3-one;DTXSID80393200;1-thioxo-4H-pyrrolo[2,1-e]imidazol-3-one;1-thioxo-1,2-dihydro-3H-pyrrolo[1,2-c]imidazol-3-one;1-Sulfanylidene-1,2-dihydro-3H-pyrrolo[1,2-c]imidazol-3-one

Suppliers and Price of 1,2-Dihydro-1-thioxo-3H-pyrrolo[1,2-c]imidazol-3-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of 1,2-Dihydro-1-thioxo-3H-pyrrolo[1,2-c]imidazol-3-one

Chemical Property:

PSA：69.61000
LogP:0.37490
XLogP3:0.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:152.00443393
Heavy Atom Count:10
Complexity:204

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CN2C(=C1)C(=S)NC2=O

Technology Process of 1,2-Dihydro-1-thioxo-3H-pyrrolo[1,2-c]imidazol-3-one

There total 1 articles about 1,2-Dihydro-1-thioxo-3H-pyrrolo[1,2-c]imidazol-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 37488-53-2
2-thiocarboxypyrrole-1-carboxylic acid imide

Guidance literature:: Pyrrol 1, Chinolin, Δ;
DOI:10.1021/jo00944a012

Reference yield: 46.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 37488-53-2
2-thiocarboxypyrrole-1-carboxylic acid imide

: dichloro(triphenylphosphine)(2-thiocarboxy-pyrrole-1-carboxylic acid imide)2 ruthenium(II)}*CH₂Cl₂

Guidance literature:: In dichloromethane; a soln. of CH2Cl2 containing RuCl2(PPh3)3 and the ligand was refluxed under dry N2 for 3 h; evapn. (vac.), dissolving in minimum CH2Cl2 followed by addn. of petroleum ether with stirring, standing for 1-2 h, centrifugation, washing several times with petroleum ether and drying in vac.; elem. anal.;

Reference yield: 42.0%

: (η5-C5H5)RuCl(SbPh3)2

: 37488-53-2
2-thiopyrrole-1,2-dicarboximide

: (C₅H₅)RuClSb(C₆H₅)3NCHCHCHCC(SH)NCO*0.5(CH₂Cl₂)

Guidance literature:: In methanol; byproducts: Sb(C6H5)3; stirring (methanol, 2-3 h, N2); concg. to near dryness, extn. (CH2Cl2), pptg. (petroleum ether, centrifugating, recrystn. (CH2Cl2-petroleum ether), filtn., washing (petroleum ether), drying in vacuo, elem. anal.;