Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, (1S,5R,6R)-

Base Information

Chemical Name:Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, (1S,5R,6R)-
CAS No.:38043-83-3
Molecular Formula:C10H16O
Molecular Weight:152.236
Hs Code.:
DSSTox Substance ID:DTXSID10447129
Nikkaji Number:J596.586A
Mol file:38043-83-3.mol

Synonyms:trans-Chrysanthenol;38043-83-3;Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, (1S,5R,6R)-;DTXSID10447129

Suppliers and Price of Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, (1S,5R,6R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, (1S,5R,6R)-

Chemical Property:

PSA：20.23000
LogP:1.96950
XLogP3:1.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:152.120115130
Heavy Atom Count:11
Complexity:215

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CCC2C(C1C2(C)C)O
Isomeric SMILES:CC1=CC[C@H]2[C@H]([C@@H]1C2(C)C)O

Technology Process of Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, (1S,5R,6R)-

There total 5 articles about Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, (1S,5R,6R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 107514-23-8
7,7-dimethyl-2-methylenebicyclo<3.1.1>heptan-6-one

trans-chrysanthenol: 19890-11-0,33644-17-6,38043-83-3,55722-60-6,74033-48-0,80581-42-6,111957-76-7
trans-chrysanthenol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; at 25 ℃;
DOI:10.1021/jo00384a035

Reference yield:

: 4698-08-2
(E)-geranic acid

trans-chrysanthenol: 19890-11-0,33644-17-6,38043-83-3,55722-60-6,74033-48-0,80581-42-6,111957-76-7
trans-chrysanthenol

Guidance literature:: Multi-step reaction with 3 steps

1: oxalyl chloride / benzene / a) 25 deg C, 2 h, b) 45 deg C, 30 min

2: 43 percent / Et₃N / toluene / 3 h / Heating

3: 67 percent / LAH / tetrahydrofuran / 25 °C

With lithium aluminium tetrahydride; oxalyl dichloride; triethylamine; In tetrahydrofuran; toluene; benzene;
DOI:10.1021/jo00384a035