ENDO-BREVICOMIN

Base Information

Chemical Name:ENDO-BREVICOMIN
CAS No.:22625-19-0
Molecular Formula:C9H16 O2
Molecular Weight:156.225
Hs Code.:
Mol file:22625-19-0.mol

Synonyms:6,8-Dioxabicyclo[3.2.1]octane,7-ethyl-5-methyl-, (1R-endo)- (8CI); (+)-endo-Brevicomin; (1R-endo)-Brevicomin;Epibrevicomin; endo-Brevicomin

Suppliers and Price of ENDO-BREVICOMIN

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of ENDO-BREVICOMIN

Chemical Property:

PSA：18.46000
LogP:2.08050

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of ENDO-BREVICOMIN

There total 6 articles about ENDO-BREVICOMIN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 505-03-3
5-oxohexanal

: 20290-99-7,21911-98-8,22625-19-0,60018-04-4,62532-53-0,64313-75-3,75716-01-7,75716-02-8,80952-67-6
exo-brevicomin

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / Et₃Al / diethyl ether / Ambient temperature; -78 deg C to

2: 90 percent / HCl / methanol

3: 65 percent / HN=NH

With hydrogenchloride; diazene; triethylaluminum; In methanol; diethyl ether;
DOI:10.1016/S0040-4039(00)85759-7

Reference yield:

: 28450-02-4
2-acetyl-6-methyl-2,3-dihydropyran

: 22625-19-0
endo-brevicomin

Guidance literature:: Multi-step reaction with 2 steps

2: baker's yeast (saccaromyces cerevisiae) / H₂O / 46 h

With baker's yeast (saccaromyces cerevisiae); In water;
DOI:10.1016/S0040-4020(01)81959-1

Reference yield:

: 109322-32-9,109429-37-0,110043-71-5
(+/-)-cis-6,7-epoxy-3-nonyn-2-one

: 21911-98-8,22625-19-0,60018-04-4,62532-53-0,64313-75-3,75716-01-7,75716-02-8,80952-67-6,20290-99-7
racem. exo-brevicomin

: 88525-42-2,62255-25-8,93426-67-6,109429-32-5,109429-39-2,110043-74-8,159912-77-3
exo-3,4-dehydrobrevicomin

Guidance literature:: (+/-)-cis-6,7-epoxy-3-nonyn-2-one; With quinoline; hydrogen; In cyclohexane; at 0 - 5 ℃; for 1h;

With zinc(II) chloride; In diethyl ether; at 0 - 5 ℃; for 0.333333h;
DOI:10.1271/bbb.110071