Cerium chloride(144CeCl3) (9CI)

Base Information

• Chemical Name: Cerium chloride(144CeCl3) (9CI)
• CAS No.: 15785-07-6
• Molecular Formula: CeCl₃
• Molecular Weight: 246.479
• Mol file: 15785-07-6.mol

Synonyms:Cerium-144chloride; Cerium-144 trichloride

Chemical Property of Cerium chloride(144CeCl3) (9CI)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cerium chloride(144CeCl3) (9CI)

There total 47 articles about Cerium chloride(144CeCl3) (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

([Ce(μ-Cl)(H2O)7](Cl)2)2 → cerium chloride (7790-86-5,15785-07-6)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Ce compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 96.4%

cerium(III) sulfate pentahydrate + ammonium chloride → cerium chloride (7790-86-5,15785-07-6)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O, NH3; a mixt. of Ce-contg. compd. and NH4Cl (2.5-fold excess) was gradually heated to 830°C under He for 12 h; chem. anal.;

DOI:10.1023/A:1027341307451

Reference yield: 96.0%

cerium(IV) oxide → cerium chloride (7790-86-5,15785-07-6)

Guidance literature:

With HCl; In hydrogenchloride; formic acid; (N2 or Ar); stirring the mixt. of CeO2, HCl (37 %) and HCOOH under reflux for 24 h;; evapn. of the soln. to dryness; dehydration of the remaining solid under vacuum (0.01 mm Hg) at ca. 170°C; for 48 h; elem. anal.;;

DOI:10.1021/om00102a011

upstream raw materials:

cerium(III) chloride heptahydrate

cerium chloride monohydrate

cerium(III) chloride hydrate

phosgene

Downstream raw materials:

1,1-dimethylethyl 4-[2-oxo-3-(4-pyridinyl)propyl]-1-piperidinecarboxylate

C₆H₅C₂CeCl₂

Ce(C₆H₅C₃N₂(CH₃)2ONHCOCH₃)2Cl₃

tris(bis(trimethylsilylamido))cerium(III)