1,1'-Binaphthalene, 2-iodo-2'-methyl-

Base Information

Chemical Name:1,1'-Binaphthalene, 2-iodo-2'-methyl-
CAS No.:402718-90-5
Molecular Formula:C21H15I
Molecular Weight:
Hs Code.:

Synonyms:

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Chemical Property of 1,1'-Binaphthalene, 2-iodo-2'-methyl-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of 1,1'-Binaphthalene, 2-iodo-2'-methyl-

There total 1 articles about 1,1'-Binaphthalene, 2-iodo-2'-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

: 70595-34-5
1,1'-bis(trimethylstannyl)ferrocene

: 76905-80-1,86688-06-4,86688-07-5
(S)-2,2'-diiodo-1,1'-binaphthyl

: 402718-81-4,151735-76-1
(S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene

: 1,1''-biferrocene

: 60536-98-3,19634-89-0,32587-64-7,32834-84-7
2,2'-dimethyl-1,1'-binaphthyl

: 402718-90-5
2-iodo-2'-methyl-1,1'-binaphthyl

Guidance literature:: With triphenylphosphine; lithium chloride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; a soln. of ferrocene in THF was added to a suspn. of biphenyl, PPh3 and LiCl in THF, the mixt. was heated to reflux for 48 h, cooled to room temp. (Ar); diluted with CH2Cl2, washed with 10% aq. HCl, water, with brine, dried over MgSO4, the solvent was removed in vac., chromd. on silica gel (isohexane; isohexane-CH2Cl2);
DOI:10.1016/S0022-328X(01)00926-3

Reference yield:

: 402718-90-5
2-iodo-2'-methyl-1,1'-binaphthyl

: C₂₇H₂₀I⁽¹⁺⁾*BF₄^(1-)

Guidance literature:: Multi-step reaction with 2 steps

1: sodium perborate

2: 82 percent / BF₃*Et₂O / CH₂Cl₂ / 20 °C

With sodium perborate; boron trifluoride diethyl etherate; In dichloromethane; 1: Oxidation / 2: Substitution;
DOI:10.1021/ja992236c