2-Norbornanemethanol, alpha,3,3-trimethyl-

Base Information

• Chemical Name: 2-Norbornanemethanol, alpha,3,3-trimethyl-
• CAS No.: 66062-78-0
• Molecular Formula: C₁₁H₂₀O
• Molecular Weight: 168.279
• European Community (EC) Number: 266-095-8
• DSSTox Substance ID: DTXSID4052344
• Nikkaji Number: J349.331H
• Mol file: 66062-78-0.mol

Synonyms:66062-78-0;2-Norbornanemethanol, alpha,3,3-trimethyl-;EINECS 266-095-8;alpha,3,3-Trimethyl-2-norbornanemethanol;Bicyclo(2.2.1)heptane-2-methanol, alpha,3,3-trimethyl-;Bicyclo[2.2.1]heptane-2-methanol, .alpha.,3,3-trimethyl-;alpha,3,3-Trimethylbicyclo(2.2.1)heptane-2-methanol;alpha,3,3-trimethylbicyclo[2.2.1]heptane-2-methanol;1-(3,3-dimethylbicyclo[2.2.1]hept-2-yl)ethanol;.alpha.,3,3-Trimethylbicyclo[2.2.1]heptane-2-methanol;Bicyclo[2.2.1]heptane-2-methanol, ?,3,3-trimethyl-;a,3,3 - trimethylbicyclo(2.2.1)heptane - 2 - methanol;SCHEMBL872722;DTXSID4052344;Bicyclo(2.2.1)heptane-2-methanol,alpha,3,3-trimethyl-

Chemical Property of 2-Norbornanemethanol, alpha,3,3-trimethyl-

Chemical Property:

• Boiling Point: 235.6°Cat760mmHg
• Flash Point: 104.5°C
• PSA: 20.23000
• Density: 0.952g/cm³
• LogP: 2.43950
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 168.151415257
• Heavy Atom Count: 12
• Complexity: 185

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C1C2CCC(C2)C1(C)C)O

Technology Process of 2-Norbornanemethanol, alpha,3,3-trimethyl-

There total 4 articles about 2-Norbornanemethanol, alpha,3,3-trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(3,3-Dimethyl-2-exo-norbornyl)-ethanone (15780-34-4,15820-33-4,42370-07-0,134591-16-5,134591-40-5) → exo-1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-ethanol (66062-78-0,134591-10-9,134591-24-5,134591-25-6,134591-26-7)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1002/ardp.19783110106

Reference yield:

endo-2,2-dimethylbicyclo<2.2.1>heptane-3-carboxylic acid (85506-67-8) → exo-1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-ethanol (66062-78-0,134591-10-9,134591-24-5,134591-25-6,134591-26-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 83 percent / diethyl ether / 3 h / Heating

2: LiAlH₄ / diethyl ether / 1 h / Heating; further reagents: NaBH₄

With lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1007/BF00809157

Reference yield:

1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon (15780-34-4,15820-33-4,42370-07-0,134591-16-5,134591-40-5) → exo-1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-ethanol (66062-78-0,134591-10-9,134591-24-5,134591-25-6,134591-26-7) + endo-1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-ethanol

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 1h; Yield given. Yields of byproduct given; Heating; further reagents: NaBH₄;

DOI:10.1007/BF00809157

upstream raw materials:

ω-methyl camphene

1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon

1-(3,3-Dimethyl-2-exo-norbornyl)-ethanone

endo-2,2-dimethylbicyclo<2.2.1>heptane-3-carboxylic acid

Downstream raw materials:

1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon

1-(3,3-Dimethyl-2-exo-bicyclo<2.2.1>heptyl)-ethylcinnamylat

1-(3,3-Dimethyl-2-exo-norbornyl)-ethanone