2-[[4-(2-methylbutan-2-yl)phenoxy]methyl]oxirane

Base Information

• Chemical Name: 2-[[4-(2-methylbutan-2-yl)phenoxy]methyl]oxirane
• CAS No.: 50605-34-0
• Molecular Formula: C14H20O2
• Molecular Weight: 220.3074
• Hs Code.: 2910900090
• Mol file: 50605-34-0.mol

Synonyms:

Chemical Property of 2-[[4-(2-methylbutan-2-yl)phenoxy]methyl]oxirane

Chemical Property:

• Vapor Pressure: 0.00101mmHg at 25°C
• Boiling Point: 311.8°Cat760mmHg
• Flash Point: 115.9°C
• PSA: 21.76000
• Density: 1.015g/cm³
• LogP: 3.15180

Purity/Quality:

99%min ^*data from raw suppliers

2-[[4-(2-METHYLBUTAN-2-YL)PHENOXY]METHYL]OXIRANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-[[4-(2-methylbutan-2-yl)phenoxy]methyl]oxirane

There total 3 articles about 2-[[4-(2-methylbutan-2-yl)phenoxy]methyl]oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3-[4-(1',1''-dimethylpropyl)phenoxy]-1,2-propanediol (90965-51-8) → 2-oxiranylmethyl 4-(1',1''-dimethylpropyl)phenyl ether (50605-34-0)

Guidance literature:

With 1H-imidazole; iodine; triphenylphosphine; In tetrahydrofuran; at -8 - 15 ℃; for 4h;

DOI:10.1080/07328300008544145

Reference yield:

1-allyloxy-4-(1',1''-dimethylpropyl)benzene (261618-80-8) → 2-oxiranylmethyl 4-(1',1''-dimethylpropyl)phenyl ether (50605-34-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / OsO₄; N-methylmorpholine-N-oxide monohydrate / acetone; H₂O / 24 h / 20 °C

2: 85 percent / imidazole; triphenylphosphine; iodine / tetrahydrofuran / 4 h / -8 - 15 °C

With 1H-imidazole; osmium(VIII) oxide; iodine; 4-methylmorpholine N-oxide; triphenylphosphine; In tetrahydrofuran; water; acetone;

DOI:10.1080/07328300008544145

Reference yield:

→ 2-oxiranylmethyl 4-(1',1''-dimethylpropyl)phenyl ether (50605-34-0)

Guidance literature:

upstream raw materials:

3-[4-(1',1''-dimethylpropyl)phenoxy]-1,2-propanediol

1-allyloxy-4-(1',1''-dimethylpropyl)benzene

Refernces

• 1、 Mereyala, Hari Babu,Goud, P. Mallikarjun,Gadikota, Rajendrakumar Reddy,Reddy, K. Ramasubba. "Transformation of terminal diols of cyclic and acyclic saccharides to epoxides and alkenes by reaction with triphenylphosphine, imidazole and iodine". . p. 1211 - 1222. Retrieved 2007/10/03.