dl-10,11-Dihydro-5,10-imino-(5H)-dibenzo(a,d)cycloheptene

Base Information

Chemical Name:dl-10,11-Dihydro-5,10-imino-(5H)-dibenzo(a,d)cycloheptene
CAS No.:50537-17-2
Molecular Formula:C15H13N
Molecular Weight:207.275
Hs Code.:
DSSTox Substance ID:DTXSID40964753
Nikkaji Number:J354.060J,J273.652G
ChEMBL ID:CHEMBL10656

Synonyms:CHEMBL10656;(+-)-10,11-Dihydro-5H-dibenzo(a,d)cyclohepten-5,10-imine;dl-10,11-Dihydro-5,10-imino-(5H)-dibenzo(a,d)cycloheptene;5H-Dibenzo(a,d)cyclohepten-5,10-imine, 10,11-dihydro-, (+-)-;50537-17-2;SCHEMBL2745287;DTXSID40964753;BDBM50007739;LS-60777;10,11-Dihydro-5H-dibenzo[a,d]cyclohepten-5,10-imine;10,11-Dihydro-5H-5,10-epiminodibenzo[a,d][7]annulene;(+)-10,11-dihydro-5h-5,10-epiminodibenzo[a,d][7]annulene;(+)-10,11-Dihydro-5H-dibenzo[a,d]cyclohepten-5,10-imine;16-azatetracyclo[7.6.1.02,7.010,15]hexadeca-2(7),3,5,10(15),11,13-hexaene;16-azatetracyclo[7.6.1.02,7.010,15]hexadeca-2(7),3,5,10,12,14-hexaene

Suppliers and Price of dl-10,11-Dihydro-5,10-imino-(5H)-dibenzo(a,d)cycloheptene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of dl-10,11-Dihydro-5,10-imino-(5H)-dibenzo(a,d)cycloheptene

Chemical Property:

Vapor Pressure:0.000234mmHg at 25°C
Boiling Point:325.2°Cat760mmHg
Flash Point:158.8°C
Density:1.16g/cm³
XLogP3:2.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:207.104799419
Heavy Atom Count:16
Complexity:275

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C2C3=CC=CC=C3C(N2)C4=CC=CC=C41

Technology Process of dl-10,11-Dihydro-5,10-imino-(5H)-dibenzo(a,d)cycloheptene

There total 5 articles about dl-10,11-Dihydro-5,10-imino-(5H)-dibenzo(a,d)cycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 113646-64-3
anti-12-hydroxy-10,11-dihydro-5H-dibenzocyclohepten-5,10-imine

: 50537-17-2
10,11-dihydro-5H-dibenzocyclohepten-5,10-imine

Guidance literature:: With hydrogenchloride; hydrogen; palladium on activated charcoal; In acetic acid; at 60 ℃; for 1.5h; under 2068.6 Torr;
DOI:10.1021/jo00243a031

Reference yield:

: C₁₇H₁₄F₃NO₂S

: 50537-17-2
10,11-dihydro-5H-dibenzocyclohepten-5,10-imine

Guidance literature:: With sodium methylate; In acetonitrile; Heating;
DOI:10.1021/ja00259a052

Reference yield:

: 10354-00-4
5H-dibenzo[a,d]cyclohepten-5-ol

: 50537-17-2
10,11-dihydro-5H-dibenzocyclohepten-5,10-imine

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / hydroxylamine hydrochloride, sodium acetate, dichloroacetic acid / CH₂Cl₂; propan-2-ol / 0.5 h / Ambient temperature

2: n-butyllithium / tetrahydrofuran; hexane; dimethylsulfoxide / 2.5 h / Heating

3: 89 percent / conc. HCl, H₂ / 5percent Pd/C / acetic acid / 1.5 h / 60 °C / 2068.6 Torr

With hydrogenchloride; dichloro-acetic acid; n-butyllithium; hydroxylamine hydrochloride; hydrogen; sodium acetate; palladium on activated charcoal; In tetrahydrofuran; hexane; dichloromethane; acetic acid; dimethyl sulfoxide; isopropyl alcohol;
DOI:10.1021/jo00243a031