3-Buten-2-ol, 1-(triphenylmethoxy)-, (2S)-

Base Information

Chemical Name:3-Buten-2-ol, 1-(triphenylmethoxy)-, (2S)-
CAS No.:403985-96-6
Molecular Formula:C23H22O2
Molecular Weight:330.426
Hs Code.:
DSSTox Substance ID:DTXSID70467424
Nikkaji Number:J1.919.658E
Mol file:403985-96-6.mol

Synonyms:3-Buten-2-ol, 1-(triphenylmethoxy)-, (2S)-;403985-96-6;(2S)-1-Trityloxybut-3-en-2-ol;SCHEMBL993538;(s)-1-trityloxybut-3-en-2-ol;DTXSID70467424;BXJGLPROAVAGKO-QFIPXVFZSA-N

Suppliers and Price of 3-Buten-2-ol, 1-(triphenylmethoxy)-, (2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 3-Buten-2-ol, 1-(triphenylmethoxy)-, (2S)-

Chemical Property:

PSA：29.46000
LogP:4.54200
XLogP3:4.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:330.161979940
Heavy Atom Count:25
Complexity:341

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CC(COC(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)O
Isomeric SMILES:C=C[C@@H](COC(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)O

Technology Process of 3-Buten-2-ol, 1-(triphenylmethoxy)-, (2S)-

There total 5 articles about 3-Buten-2-ol, 1-(triphenylmethoxy)-, (2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 129940-50-7
(S)-tritylglycidol

: 403985-96-6
(S)-1-(triphenylmethoxy)-3-buten-2-ol

Guidance literature:: With n-butyllithium; trimethylsulphonium iodide; In tetrahydrofuran; at -60 - 20 ℃; for 4h; Inert atmosphere;

Reference yield: 92.0%

: 949583-79-3
(E)-methyl (4-(trityloxy)but-2-en-1-yl)carbonate

: 403985-96-6
(S)-1-(triphenylmethoxy)-3-buten-2-ol

Guidance literature:: With CF₃O₃S^(1-)*C₅₆H₄₈IrNO₂P⁽¹⁺⁾; potassium hydrogencarbonate; In water; N,N-dimethyl-formamide; at 20 ℃; for 3.5h; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/ja109953v

Reference yield: 83.0%

: 2181-42-2
trimethylsulphonium iodide

: 129940-50-7
(S)-tritylglycidol

: 403985-96-6
(S)-1-(triphenylmethoxy)-3-buten-2-ol

Guidance literature:: trimethylsulphonium iodide; With n-butyllithium; In tetrahydrofuran; at -50 ℃; Inert atmosphere;

(S)-tritylglycidol; In tetrahydrofuran; at -10 ℃; Inert atmosphere;
DOI:10.1021/acs.oprd.0c00369