Picein

Base Information

Chemical Name:Picein
CAS No.:530-14-3
Molecular Formula:C14H18O7
Molecular Weight:298.293
Hs Code.:
European Community (EC) Number:208-473-7
UNII:2H3ACT49CQ
DSSTox Substance ID:DTXSID201031535
Nikkaji Number:J6.697D
Wikipedia:Picein
Wikidata:Q7190609
Metabolomics Workbench ID:68000
ChEMBL ID:CHEMBL1512620
Mol file:530-14-3.mol

Synonyms:beta-glucopyrane-4-oxyacetophenone;picein

Suppliers and Price of Picein

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
4-Acetylphenyl-b-D-glucopyranoside
10mg
$ 340.00

TRC
4-Acetylphenylβ-D-Glucopyranoside
50mg
$ 175.00

Sigma-Aldrich
Picein analytical standard
10mg
$ 286.00

Medical Isotopes, Inc.
4-Acetylphenylβ-D-Glucopyranoside
50 mg
$ 870.00

Medical Isotopes, Inc.
4-Acetylphenylβ-D-Glucopyranoside
500 mg
$ 1960.00

Matrix Scientific
Ethanone 1-[4-(2-azidoethoxy)-3-methoxyphenyl]-95%
1g
$ 990.00

Matrix Scientific
Ethanone 1-[4-(2-azidoethoxy)-3-methoxyphenyl]-95%
5g
$ 1816.00

Biosynth Carbosynth
4-Acetylphenyl-b-D-glucopyranoside
50 mg
$ 125.00

Biosynth Carbosynth
4-Acetylphenyl-b-D-glucopyranoside
25 mg
$ 95.00

Biosynth Carbosynth
4-Acetylphenyl-b-D-glucopyranoside
10 mg
$ 50.00

Total 31 raw suppliers

Chemical Property of Picein

Chemical Property:

Appearance/Colour:pale yellow solid
Melting Point:195 °C
Refractive Index:1.6380 (estimate)
Boiling Point:562.6 °C at 760 mmHg
PKA:12.71±0.70(Predicted)
Flash Point:213.2 °C
PSA：116.45000
Density:1.433 g/cm³
LogP:-0.93210
Storage Temp.:Hygroscopic, -20?C Freezer, Under Inert Atmosphere
Solubility.:Ethanol (Slightly), Methanol (Slightly), Water (Slightly)
XLogP3:-0.7
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:4
Exact Mass:298.10525291
Heavy Atom Count:21
Complexity:353

Purity/Quality:

≥98% ^*data from raw suppliers

4-Acetylphenyl-b-D-glucopyranoside ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)C1=CC=C(C=C1)OC2C(C(C(C(O2)CO)O)O)O
Isomeric SMILES:CC(=O)C1=CC=C(C=C1)O[C@H]2[C@@H]([C@H]([C@@H]([C@H](O2)CO)O)O)O

Technology Process of Picein

There total 8 articles about Picein which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 25876-45-3
p-hydroxyacetophenone-4-O-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranoside

: 530-14-3
picein

Guidance literature:: With water; triethylamine; In methanol; Ambient temperature;
DOI:10.1016/0031-9422(95)00219-7

Reference yield: 43.0%

: 530-14-3
picein

Guidance literature:: With methanol; In dichloromethane; for 0.333333h;

With sodium methylate; In dichloromethane;

Reference yield:

: 99-93-4
4-Hydroxyacetophenone

: 530-14-3
picein

Guidance literature:: Multi-step reaction with 2 steps

1: 42 percent / KOH; triethylbenzylammonium chloride / CHCl₃; H₂O / Heating

2: 56 percent / 1M NaOMe / methanol

With potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; sodium methylate; In methanol; chloroform; water; 1: Koenigs-Knorr reaction;
DOI:10.1023/A:1013971214679