Carbamodithioic acid, (phenylmethyl)-, monoammonium salt

Base Information

• Chemical Name: Carbamodithioic acid, (phenylmethyl)-, monoammonium salt
• CAS No.: 41270-27-3
• Molecular Formula: C8H9NS2.H3N
• Molecular Weight: 200.329
• Mol file: 41270-27-3.mol

Synonyms:

Chemical Property of Carbamodithioic acid, (phenylmethyl)-, monoammonium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamodithioic acid, (phenylmethyl)-, monoammonium salt

There total 1 articles about Carbamodithioic acid, (phenylmethyl)-, monoammonium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

carbon disulfide (75-15-0,12122-00-8) + benzylamine (100-46-9) → N-benzyl-dithiocarbamic acid ammonium salt (41270-27-3)

Guidance literature:

With ammonia; at 0 ℃; for 1h;

DOI:10.1039/c6ra08785j

Reference yield: 89.0%

N-benzyl-dithiocarbamic acid ammonium salt (41270-27-3) + chloroacetic acid (79-11-8) → 3-benzylrhodanine (10574-69-3)

Guidance literature:

N-benzyl-dithiocarbamic acid ammonium salt; chloroacetic acid; With sodium carbonate; sodium hydroxide; In water; at 5 - 10 ℃; for 1h;

With hydrogenchloride; In water; at 80 - 85 ℃; for 0.25h;

DOI:10.1039/c6ra08785j

Reference yield: 86.0%

(E)-2-(4-bromobenzylidene)cyclohexan-1-one (111729-78-3) + N-benzyl-dithiocarbamic acid ammonium salt (41270-27-3) → 2-(α-(N-benzyl-thiocarbamoylthio)-4-bromobenzyl)-cyclohexan-1-one (139938-24-2)

Guidance literature:

With hydrogenchloride; In methanol; acetone; at -5 ℃; for 4h;

DOI:10.1007/BF00811113

upstream raw materials:

carbon disulfide

benzylamine

Downstream raw materials:

N-benzyl-3-oxobutanamide

2-(α-(N-benzyl-thiocarbamoylthio)-4-methoxybenzyl)-cyclohexan-1-one

2,2,4-Trimethyl-3-oxo-valeriansaeurebenzylamid

ethyl 3-benzyl-4-hydroxy-2-thioxothiazolidine-4-acetate