2-(2-Methyl-2-propen-1-yl)-1,3-cyclohexanedione

Base Information

Chemical Name:2-(2-Methyl-2-propen-1-yl)-1,3-cyclohexanedione
CAS No.:42738-69-2
Molecular Formula:C10H14O2
Molecular Weight:166.22
Hs Code.:
DSSTox Substance ID:DTXSID201241584

Synonyms:2-(2-Methyl-2-propen-1-yl)-1,3-cyclohexanedione;DTXSID201241584;42738-69-2

Suppliers and Price of 2-(2-Methyl-2-propen-1-yl)-1,3-cyclohexanedione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(2-Methyl-2-propen-1-yl)-1,3-cyclohexanedione

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:166.099379685
Heavy Atom Count:12
Complexity:212

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=C)CC1C(=O)CCCC1=O

Technology Process of 2-(2-Methyl-2-propen-1-yl)-1,3-cyclohexanedione

There total 1 articles about 2-(2-Methyl-2-propen-1-yl)-1,3-cyclohexanedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1458-98-6
2-methyl-3-bromo-1-propene

: 30182-67-3
1,3-Cyclohexanedione

: 42738-69-2
2-(2-methyl-2-propenyl)-1,3-cyclohexanedione

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In water; at 60 ℃; Inert atmosphere;
DOI:10.1021/acs.orglett.7b02159

Reference yield: 65.0%

: 42738-69-2
2-(2-methyl-2-propenyl)-1,3-cyclohexanedione

: 100-46-9
benzylamine

: 1161395-77-2
3-benzylamino-2-(2-methylprop-2-enyl)cyclohex-2-enone

Guidance literature:: With toluene-4-sulfonic acid; In benzene; for 18h; Reflux;
DOI:10.3184/030823408X314013

Reference yield:

: 42738-69-2
2-(2-methyl-2-propenyl)-1,3-cyclohexanedione

: cyclohexyl (5,7-dihydroxy-2,2-dimethyl-2,3,3a,4-tetrahydro-4,9a-propanofuro[2,3-b]chromen-6-yl)methanone

: cyclohexyl (5,7-dihydroxy-2,2-dimethyl-2,3,3a,4-tetrahydro-4,9a-propanofuro[2,3-b]chromen-8-yl)methanone

Guidance literature:: Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / toluene / 0.5 h / 90 °C / Inert atmosphere

2: lithium aluminium tetrahydride / tetrahydrofuran / 0.5 h / 20 °C / Inert atmosphere

3: trifluoroacetic acid / toluene / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; toluene-4-sulfonic acid; trifluoroacetic acid; In tetrahydrofuran; toluene;
DOI:10.1021/acs.orglett.7b02159