Technology Process of 2-Nonen-1-ol, 2-methyl-, (E)-
There total 1 articles about 2-Nonen-1-ol, 2-methyl-, (E)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C17H24O3;
With
bis(cyclopentadienyl)titanium (III) chloride;
In
tetrahydrofuran;
at 20 ℃;
for 0.5h;
Inert atmosphere;
With
sodium dihydrogenphosphate; water;
In
tetrahydrofuran;
at 20 ℃;
for 0.333333h;
Inert atmosphere;
DOI:10.1002/ejoc.200901222
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: C37H40NOPRh; hydrogen / dichloromethane / 16 h / 0 °C / 37503.8 Torr / Schlenk technique
2.1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 2 h / 0 °C / Schlenk technique; Inert atmosphere
3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 0 - 20 °C / Schlenk technique; Inert atmosphere
4.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.17 h / -78 - -40 °C / Schlenk technique; Inert atmosphere
4.2: 0.5 h / -78 - -40 °C / Schlenk technique; Inert atmosphere
5.1: diisobutylaluminium hydride / dichloromethane / 0.5 h / Schlenk technique; Inert atmosphere
6.1: C37H40NOPRh; hydrogen / dichloromethane / 16 h / 0 °C / 37503.8 Torr / Schlenk technique
7.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 - -60 °C / Schlenk technique; Inert atmosphere
8.1: potassium hexamethylsilazane / tetrahydrofuran / 0.17 h / -78 - -40 °C / Schlenk technique; Inert atmosphere
8.2: 0.5 h / -78 - -40 °C / Schlenk technique; Inert atmosphere
With
oxalyl dichloride; di-isopropyl azodicarboxylate; hydrogen; C37H40NOPRh; potassium hexamethylsilazane; diisobutylaluminium hydride; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.202104759
- Guidance literature:
-
Multi-step reaction with 3 steps
1: C37H40NOPRh; hydrogen / dichloromethane / 16 h / 0 °C / 37503.8 Torr / Schlenk technique
2: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 2 h / 0 °C / Schlenk technique; Inert atmosphere
3: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 0 - 20 °C / Schlenk technique; Inert atmosphere
With
di-isopropyl azodicarboxylate; hydrogen; C37H40NOPRh; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine;
In
tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.202104759
