tert-Butyl[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane

Base Information

Chemical Name:tert-Butyl[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane
CAS No.:439692-57-6
Molecular Formula:C23H32OSi
Molecular Weight:352.592
Hs Code.:
DSSTox Substance ID:DTXSID30705470
Nikkaji Number:J1.916.589B
Wikidata:Q82638344

Synonyms:439692-57-6;tert-Butyl[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane;SCHEMBL5065409;DTXSID30705470;1-(tert-Butyldiphenylsiloxy)-2,2-dimethyl-4-pentene

Suppliers and Price of tert-Butyl[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of tert-Butyl[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:8
Exact Mass:352.222242174
Heavy Atom Count:25
Complexity:390

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OCC(C)(C)CC=C

Technology Process of tert-Butyl[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane

There total 7 articles about tert-Butyl[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 3420-42-6
2,2-dimethylpent-4-en-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 439692-57-6
(tert-butyl)[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 20 ℃;
DOI:10.1021/ja028921s

Reference yield:

: 76352-72-2
methyl 2,2-dimethyl-4-pentenoate

: 439692-57-6
(tert-butyl)[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / LiAlH₄ / diethyl ether / 3 h / Heating

2: 82 percent / imidazole / CH₂Cl₂ / 20 °C

With 1H-imidazole; lithium aluminium tetrahydride; In diethyl ether; dichloromethane;
DOI:10.1021/ja028921s

Reference yield:

: (E)-((5-bromo-2,2-dimethylpent-3-en-1-yl)oxy)(tertbutyl)diphenylsilane

: C₂₃H₃₂OSi

: 439692-57-6
(tert-butyl)[(2,2-dimethylpent-4-en-1-yl)oxy]diphenylsilane

Guidance literature:: With 1-allyl-2,2,3-trimethyl-1-phenylphosphetanium bromide; lithium tri-t-butoxyaluminum hydride; In tetrahydrofuran; toluene; at 90 ℃; for 16h;
DOI:10.1021/jacs.5b01899