2-[3-Bromo-5-[2,4,6-tri(propan-2-yl)phenyl]phenyl]-1,3,5-tri(propan-2-yl)benzene

Base Information

Chemical Name:2-[3-Bromo-5-[2,4,6-tri(propan-2-yl)phenyl]phenyl]-1,3,5-tri(propan-2-yl)benzene
CAS No.:443295-47-4
Molecular Formula:C36H49Br
Molecular Weight:561.689
Hs Code.:
DSSTox Substance ID:DTXSID80514296
Nikkaji Number:J2.288.662B
Wikidata:Q82374535

Synonyms:443295-47-4;DTXSID80514296;2~5~-Bromo-1~2~,1~4~,1~6~,3~2~,3~4~,3~6~-hexa(propan-2-yl)-1~1~,2~1~:2~3~,3~1~-terphenyl

Suppliers and Price of 2-[3-Bromo-5-[2,4,6-tri(propan-2-yl)phenyl]phenyl]-1,3,5-tri(propan-2-yl)benzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-[3-Bromo-5-[2,4,6-tri(propan-2-yl)phenyl]phenyl]-1,3,5-tri(propan-2-yl)benzene

Chemical Property:

XLogP3:12.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:8
Exact Mass:560.30176
Heavy Atom Count:37
Complexity:582

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC(=CC(=C2)Br)C3=C(C=C(C=C3C(C)C)C(C)C)C(C)C)C(C)C

Technology Process of 2-[3-Bromo-5-[2,4,6-tri(propan-2-yl)phenyl]phenyl]-1,3,5-tri(propan-2-yl)benzene

There total 1 articles about 2-[3-Bromo-5-[2,4,6-tri(propan-2-yl)phenyl]phenyl]-1,3,5-tri(propan-2-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 21521-51-7
2,4,6-tribromoiodobenzene

: 21524-34-5
2,4,6-triisopropyl-1-bromobenzene

: 717-74-8
1,3,5-triisopropyl benzene

: 443295-47-4
5'-bromo-2,4,6,2'',4'',6''-hexaisopropyl-1,1:3',1''-terphenyl

Guidance literature:: 2,4,6-triisopropyl-1-bromobenzene; With 1,2-dibrom-methane; magnesium; In tetrahydrofuran; for 3.5h; Heating;

2,4,6-tribromoiodobenzene; In tetrahydrofuran; for 5h; Further stages.; Heating;
DOI:10.1021/ja020186x

Reference yield: 88.0%

: 29841-69-8
(S,S)-1,2-diphenyl-1,2-diaminoethane

: 443295-47-4
5'-bromo-2,4,6,2'',4'',6''-hexaisopropyl-1,1:3',1''-terphenyl

: 1353901-26-4
3,5-bis(2,4,6-triisopropylbenzene)((1S, 2S)-2-amino-1,2-diphenylethylamino)benzene

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; In tetrahydrofuran; at 80 ℃; for 18h; Inert atmosphere; Glovebox;
DOI:10.1021/jacs.9b05465

Reference yield: 77.0%

: 443295-47-4
5'-bromo-2,4,6,2'',4'',6''-hexaisopropyl-1,1:3',1''-terphenyl

: bis(2,2'',4,4'',6,6''-hexaisopropyl-[1,1':3',1''-terphenyl]-5'-yl)phosphine oxide

Guidance literature:: 5'-bromo-2,4,6,2'',4'',6''-hexaisopropyl-1,1:3',1''-terphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.91667h; Inert atmosphere;

With diethylphosphoramidous dichloride; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 19h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; hexane; water; at 0 - 20 ℃; for 7.5h; Inert atmosphere;
DOI:10.1021/jacs.1c05769