9-Decen-1-ol, 9-bromo-

Base Information

• Chemical Name: 9-Decen-1-ol, 9-bromo-
• CAS No.: 455272-23-8
• Molecular Formula: C₁₀H₁₉BrO
• Molecular Weight: 235.164
• Mol file: 455272-23-8.mol

Synonyms:

Chemical Property of 9-Decen-1-ol, 9-bromo-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-Decen-1-ol, 9-bromo-

There total 1 articles about 9-Decen-1-ol, 9-bromo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 9-bromo-dec-9-en-1-ol (455272-23-8) + 9-decyn-1-ol (17643-36-6)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol; at 40 ℃; for 24h; Reflux;

Reference yield:

9-bromo-dec-9-en-1-ol (455272-23-8) → 1-(8-Benzenesulfonyloxyoctyl)-cyclopropene

Guidance literature:

Multi-step reaction with 5 steps

1: toluene-4-sulfonic acid / diethyl ether / -10 - 10 °C

2: potassium hydroxide / N,N'-dibenzyl-N,N,N',N'-tetramethylethylenediammonium dibromide / dichloromethane / 96 h / 20 °C

3: hydrogenchloride; toluene-4-sulfonic acid / methanol; water / 1 h / 20 °C

4: pyridine / dichloromethane / 37 h / -20 - 20 °C / Cooling with acetone-dry ice

5: methyllithium / diethyl ether / 0.25 h / 0 °C

With pyridine; hydrogenchloride; potassium hydroxide; methyllithium; toluene-4-sulfonic acid; N,N'-dibenzyl-N,N,N',N'-tetramethylethylenediammonium dibromide; In methanol; diethyl ether; dichloromethane; water;

Reference yield:

9-bromo-dec-9-en-1-ol (455272-23-8) → 1-(8-(4-methylphenylthio)octyl)-cyclopropene

Guidance literature:

Multi-step reaction with 5 steps

1.1: toluene-4-sulfonic acid / diethyl ether / -10 - 10 °C

2.1: potassium hydroxide / N,N'-dibenzyl-N,N,N',N'-tetramethylethylenediammonium dibromide / dichloromethane / 96 h / 20 °C

3.1: hydrogenchloride; toluene-4-sulfonic acid / methanol; water / 1 h / 20 °C

4.1: pyridine / dichloromethane / 37 h / -20 - 20 °C / Cooling with acetone-dry ice

5.1: potassium tert-butylate / N,N-dimethyl-formamide / 0.25 h / 20 °C

5.2: 2 h / 20 °C

With pyridine; hydrogenchloride; potassium hydroxide; potassium tert-butylate; toluene-4-sulfonic acid; N,N'-dibenzyl-N,N,N',N'-tetramethylethylenediammonium dibromide; In methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide;

Downstream raw materials:

1-(8-benzenesulfonyloxyoctyl)-1,2,2-tribromo-cyclopropane