decahydro-2,5-methanocyclopropa[a]indene

Base Information

• Chemical Name: decahydro-2,5-methanocyclopropa[a]indene
• CAS No.: 45848-45-1
• Molecular Formula: C11H16
• Mol file: 45848-45-1.mol

Synonyms:

Chemical Property of decahydro-2,5-methanocyclopropa[a]indene

Chemical Property:

• Vapor Pressure: 0.317mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of decahydro-2,5-methanocyclopropa[a]indene

There total 4 articles about decahydro-2,5-methanocyclopropa[a]indene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetracyclo<6.2.1.02,7.03,5>undec-9-ene (1777-42-0,139627-84-2) → Tetracyclo<6.2.1.02,703,5>undecane (1777-44-2,45848-45-1,114028-44-3)

Guidance literature:

With hydrogen; nickel; In methanol; for 4h; under 2280 Torr; Ambient temperature;

Reference yield:

endo-Dicyclopentadien (1755-01-7,25038-78-2) → Tetracyclo<6.2.1.02,703,5>undecane (1777-44-2,45848-45-1,114028-44-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 65 percent / 25percent aq. NaOH / triethylbenzylammonium chloride / 3 h / Heating

2: 65 percent / Li, tert-butyl alcohol / diethyl ether / 3 h / Heating

3: 95 percent / H₂ / Raney nickel / methanol / 4 h / 2280 Torr / Ambient temperature

With sodium hydroxide; hydrogen; lithium; tert-butyl alcohol; N-benzyl-N,N,N-triethylammonium chloride; nickel; In methanol; diethyl ether;

Reference yield:

4,4-Dichlorotetracyclo<6.2.1.02,703,5>undec-9-ene (3762-19-4,18906-12-2,139629-35-9) → Tetracyclo<6.2.1.02,703,5>undecane (1777-44-2,45848-45-1,114028-44-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / Li, tert-butyl alcohol / diethyl ether / 3 h / Heating

2: 95 percent / H₂ / Raney nickel / methanol / 4 h / 2280 Torr / Ambient temperature

With hydrogen; lithium; tert-butyl alcohol; nickel; In methanol; diethyl ether;

upstream raw materials:

tetracyclo<6.2.1.0^2,7.0^3,5>undec-9-ene

endo-Dicyclopentadien

4,4-Dichlorotetracyclo<6.2.1.0^2,70^3,5>undec-9-ene

Refernces