2-(Methoxymethoxy)-5-methylphenylboronic acid

Base Information

Chemical Name:2-(Methoxymethoxy)-5-methylphenylboronic acid
CAS No.:478685-71-1
Molecular Formula:C9H13BO4
Molecular Weight:196.011
Hs Code.:2931900090
DSSTox Substance ID:DTXSID10681662
Nikkaji Number:J2.971.842C
Wikidata:Q82605783
Mol file:478685-71-1.mol

Synonyms:478685-71-1;2-(METHOXYMETHOXY)-5-METHYLPHENYLBORONIC ACID;(2-(Methoxymethoxy)-5-methylphenyl)boronic acid;[2-(Methoxymethoxy)-5-methylphenyl]boronic acid;SCHEMBL2703903;DTXSID10681662;MFCD17015744;AKOS006335099;BS-28573;CS-0175803;(2-(Methoxymethoxy)-5-methylphenyl)boronicacid;D71384;A872043;Dihydroxy[2-(methoxymethoxy)-5-methylphenyl]borane

Suppliers and Price of 2-(Methoxymethoxy)-5-methylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-(Methoxymethoxy)-5-methylphenylboronicAcid
100mg
$ 60.00

Crysdot
(2-(Methoxymethoxy)-5-methylphenyl)boronicacid 95+%
10g
$ 471.00

AOBChem
2-(Methoxymethoxy)-5-methylphenylboronicacid 97%
500mg
$ 59.00

Alichem
(2-(Methoxymethoxy)-5-methylphenyl)boronicacid
10g
$ 480.76

AK Scientific
2-(Methoxymethoxy)-5-methylphenylboronicacid
1g
$ 184.00

Total 10 raw suppliers

Chemical Property of 2-(Methoxymethoxy)-5-methylphenylboronic acid

Chemical Property:

PSA：58.92000
LogP:-0.34250
Storage Temp.:Refrigerated.
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:196.0906891
Heavy Atom Count:14
Complexity:165

Purity/Quality:

97% ^*data from raw suppliers

2-(Methoxymethoxy)-5-methylphenylboronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C(C=CC(=C1)C)OCOC)(O)O

Technology Process of 2-(Methoxymethoxy)-5-methylphenylboronic acid

There total 4 articles about 2-(Methoxymethoxy)-5-methylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 104750-60-9
2-bromo-1-(methoxymethoxy)-4-methylbenzene

: 478685-71-1
2-(methoxymethoxy)-5-methylbenzeneboronic acid

Guidance literature:: 2-bromo-1-(methoxymethoxy)-4-methylbenzene; With n-butyllithium; In diethyl ether; hexane; for 2h;

With Trimethyl borate; In diethyl ether; hexane; at 20 ℃; for 6h;

With hydrogenchloride; In diethyl ether; hexane; at 20 ℃; for 0.5h; Further stages.;
DOI:10.1002/chem.200601884

Reference yield: 62.0%

: 5419-55-6
Triisopropyl borate

: 25458-49-5
1-(methoxymethoxy)-4-methylbenzene

: 478685-71-1
2-(methoxymethoxy)-5-methylbenzeneboronic acid

Guidance literature:: 1-(methoxymethoxy)-4-methylbenzene; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 2h;

Triisopropyl borate; In tetrahydrofuran; hexane; for 1h;
DOI:10.1021/acs.joc.7b03111

Reference yield:

: 121-43-7,63156-11-6
Trimethyl borate

: 25458-49-5
1-(methoxymethoxy)-4-methylbenzene

: 478685-71-1
2-(methoxymethoxy)-5-methylbenzeneboronic acid

Guidance literature:: 1-(methoxymethoxy)-4-methylbenzene; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In diethyl ether; cyclohexane; at -78 ℃; for 2.5h; Inert atmosphere;

Trimethyl borate; In diethyl ether; cyclohexane; at -78 ℃; for 2h; Inert atmosphere;
DOI:10.1002/cbic.201800231