2-butylsulfanylcarbothioylsulfanylpropanoic acid

Base Information

• Chemical Name: 2-butylsulfanylcarbothioylsulfanylpropanoic acid
• CAS No.: 480436-46-2
• Molecular Formula: C8H14O2S3
• Molecular Weight: 238.396
• Mol file: 480436-46-2.mol

Synonyms:

Chemical Property of 2-butylsulfanylcarbothioylsulfanylpropanoic acid

Chemical Property:

• Vapor Pressure: 5.7E-08mmHg at 25°C

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-butylsulfanylcarbothioylsulfanylpropanoic acid

There total 1 articles about 2-butylsulfanylcarbothioylsulfanylpropanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

carbon disulfide (75-15-0,12122-00-8) + n-butanethiol (109-79-5) + 2-Bromopropionic acid (598-72-1,10327-08-9) → S-1-butyl-S'-(α-methyl-α'-acetic acid)trithiocarbonate (480436-46-2)

Guidance literature:

carbon disulfide; n-butanethiol; With sodium hydroxide; In acetone; at 20 ℃; for 0.5h;

2-Bromopropionic acid; With sodium hydroxide; In acetone; at 20 ℃; for 24h;

DOI:10.1021/ma048787r

Reference yield: 99.0%

S-1-butyl-S'-(α-methyl-α'-acetic acid)trithiocarbonate (480436-46-2) + N-Acryloylmorpholine (5117-12-4,28902-82-1) → C78H124N10O22S3

Guidance literature:

With 2,2’-azobis[2-(2-imidazolin-2-yl)propane] dihydrochloride; In 1,4-dioxane; water; at 70 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ma402435n

Reference yield: 97.0%

S-1-butyl-S'-(α-methyl-α'-acetic acid)trithiocarbonate (480436-46-2) + propargyl alcohol (107-19-7) → S-1-butyl-S'-(α-methyl-α'-propargylacetate)trithiocarbonate (1201925-03-2)

Guidance literature:

With dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 36h; Inert atmosphere;

DOI:10.1002/pola.24782

upstream raw materials:

carbon disulfide

n-butanethiol

2-Bromopropionic acid

Downstream raw materials:

S-1-butyl-S'-(α-methyl-α'-propargylacetate)trithiocarbonate

3-(trimethylsilyl)prop-2-ynyl-2-(butylthiocarbonothioylthio) propanoate

C₁₄H₂₆O₂S₄

2-(methacryloyloxy)ethyl acetoacetate

Refernces

Controlled radical polymerization of styrene-based models of the active site of the [FeFe]-hydrogenase

10.1002/pola.26584

The research focuses on the controlled radical polymerization of styrene-based models of the active site of the [FeFe]-hydrogenase, an enzyme crucial for hydrogen metabolism in certain microorganisms. The purpose of this study was to synthesize and incorporate biomimetic models of the [FeFe]-hydrogenase into copolymers using controlled radical polymerization techniques, with the aim of creating polymer-bound organometallic catalysts for efficient hydrogen production. The researchers successfully synthesized three different styrene-based model complexes, including propanedithiolato-bridged, 2-azapropanedithiolato-bridged, and bifunctional styrene iron complexes. These were copolymerized with styrene using free radical and reversible addition-fragmentation chain transfer (RAFT) polymerization methods. The resulting copolymers exhibited narrow molar mass distributions and retained the electrocatalytic proton reduction ability of the [FeFe]-hydrogenase models at a low potential of –2.2 V. The study concluded that the [FeFe]-hydrogenase mimics could be successfully incorporated into copolymers without inhibiting their catalytic ability, contributing to the development of polymer-bound metallorganic catalysts for hydrogen production. Key chemicals used in the process included various styrene-based monomers, model complexes of the [FeFe]-hydrogenase, initiators like AIBN, and RAFT agents such as 2-(butylthiocarbonothioylthio)propanoic acid (CTA2), as well as solvents like toluene and reaction media like chloroform and triethylamine.

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