2,6-DIMETHYLBENZOQUINONE 4-OXIME

Base Information

• Chemical Name: 2,6-DIMETHYLBENZOQUINONE 4-OXIME
• CAS No.: 4965-29-1
• Molecular Formula: C8H9NO2
• Molecular Weight: 151.165
• Hs Code.: 2928000090
• Mol file: 4965-29-1.mol

Synonyms:2,6-dimethylbenzo-1,4-quinone 4-oxime;2,6-dimethyl-1,4-benzoquinone 4-monooxime;2,6-Dimethylbenzo<1,2-d:5,4-d'>bisoxazol;

Chemical Property of 2,6-DIMETHYLBENZOQUINONE 4-OXIME

Chemical Property:

• Vapor Pressure: 0.001mmHg at 25°C
• Melting Point: 168-169oC
• Boiling Point: 276.175oC at 760 mmHg
• Flash Point: 120.827oC
• PSA: 49.66000
• Density: 1.161g/cm3
• LogP: 1.29190

Purity/Quality:

98%Min ^*data from raw suppliers

2,6-Dimethylbenzoquinone4-Oxime ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,6-DIMETHYLBENZOQUINONE 4-OXIME

There total 5 articles about 2,6-DIMETHYLBENZOQUINONE 4-OXIME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2,6-dimethyl-1,4-benzoquinone (527-61-7) → 2,6-dimethyl-[1,4]benzoquinone-4-oxime (4965-29-1)

Guidance literature:

With hydroxylamine hydrochloride; sodium acetate; In ethanol; for 1.5h; Reflux;

DOI:10.1016/j.tet.2014.07.088

Reference yield: 83.0%

2.6-dimethylphenol (576-26-1,25134-01-4) → 2,6-dimethyl-[1,4]benzoquinone-4-oxime (4965-29-1)

Guidance literature:

With hydrogenchloride; sodium nitrite; In ethanol; water; at 0 ℃; for 1h;

DOI:10.1016/j.tet.2014.07.088

Reference yield:

2,6-dimethylaniline (87-62-7) → 2,6-dimethyl-[1,4]benzoquinone-4-oxime (4965-29-1)

Guidance literature:

With sulfuric acid; sodium nitrite;

upstream raw materials:

2.6-dimethylphenol

2,6-dimethyl-1,4-benzoquinone

2,6-dimethylaniline

3,5-Dimethylphenol

Downstream raw materials:

2,6-Dimethyl-(1,4)benzochinon-4-oxim-methylether

3,5-dimethyl-4-hydroxyaniline

4-[(3-chlorophenyl)aminocarbonyloxyimino]-2,6-dimethylcyclohexa-2,5-dien-1-one

2,6-dimethyl-4-[(4-methylphenyl)aminocarbonyloxyimino]cyclohexa-2,5-dien-1-one