6,7-Dioxabicyclo(3.2.1)octane, 8-bromo-

Base Information

• Chemical Name: 6,7-Dioxabicyclo(3.2.1)octane, 8-bromo-
• CAS No.: 78535-39-4
• Molecular Formula: C₆H₉BrO₂
• Molecular Weight: 193.04
• DSSTox Substance ID: DTXSID80999827
• Mol file: 78535-39-4.mol

Synonyms:6,7-Dioxabicyclo(3.2.1)octane, 8-bromo-;78535-39-4;6,7-Dioxabicyclo[3.2.1]octane, 8-bromo-;8-bromo-6,7-dioxabicyclo[3.2.1]octane;DTXSID80999827

Chemical Property of 6,7-Dioxabicyclo(3.2.1)octane, 8-bromo-

Chemical Property:

• Vapor Pressure: 0.793mmHg at 25°C
• Boiling Point: 189.3°C at 760 mmHg
• Flash Point: 71.3°C
• Density: 1.616g/cm³
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 191.97859
• Heavy Atom Count: 9
• Complexity: 106

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC2C(C(C1)OO2)Br

Technology Process of 6,7-Dioxabicyclo(3.2.1)octane, 8-bromo-

There total 6 articles about 6,7-Dioxabicyclo(3.2.1)octane, 8-bromo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

cis-2,trans-3-dibromocyclohexyl hydroperoxide (72536-21-1,78549-34-5,78549-35-6,78549-39-0) → cis-8-bromo-6,7-dioxabicyclo<3.2.1>octane (78535-39-4)

Guidance literature:

With silver trifluoroacetate; In dichloromethane; for 1h;

DOI:10.1039/P19810001375

Reference yield:

cyclohex-2-enyl hydroperoxide (4845-05-0) → cis-8-bromo-6,7-dioxabicyclo<3.2.1>octane (78535-39-4)

Guidance literature:

Multi-step reaction with 2 steps

1: Br₂

2: Ag₂O

With bromine; silver(l) oxide;

DOI:10.1039/c39820000865

Reference yield:

C9H18Br2O2Si (72535-92-3) → cis-8-bromo-6,7-dioxabicyclo<3.2.1>octane (78535-39-4)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol

2: 60 percent / AgO₂CCF₃ / CH₂Cl₂ / 1 h

With silver trifluoroacetate; In methanol; dichloromethane;

DOI:10.1039/P19810001375

upstream raw materials:

cis-2,trans-3-dibromocyclohexyl hydroperoxide

2,3-Dibromo-cyclohexyl-hydroperoxide

cyclohex-2-enyl hydroperoxide

C₉H₁₈Br₂O₂Si

Downstream raw materials:

cis-2-bromo-cis-3-butoxycyclohexanol