Diethyl (1-hexadecyl)phosphonate

Base Information

• Chemical Name: Diethyl (1-hexadecyl)phosphonate
• CAS No.: 16165-71-2
• Molecular Formula: C20H43 O3 P
• Molecular Weight: 362.533
• Mol file: 16165-71-2.mol

Synonyms:Phosphonicacid, hexadecyl-, diethyl ester (6CI,7CI,8CI,9CI); Diethylhexadecanephosphonate; Diethyl hexadecylphosphonate; PAE16

Chemical Property of Diethyl (1-hexadecyl)phosphonate

Chemical Property:

• Boiling Point: 437.0±14.0 °C(Predicted)
• PSA: 45.34000
• Density: 0.916±0.06 g/cm3(Predicted)
• LogP: 7.73380

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diethyl (1-hexadecyl)phosphonate

There total 4 articles about Diethyl (1-hexadecyl)phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-Hexadecene (629-73-2) + phosphonic acid diethyl ester (762-04-9) → hexadecanphosphonic acid diethyl ester (16165-71-2)

Guidance literature:

With di-tert-butyl peroxide; at 135 ℃; for 8h;

DOI:10.1080/10426500210664

Reference yield:

hexadecanyl bromide (112-82-3) + triethyl phosphite (122-52-1) → hexadecanphosphonic acid diethyl ester (16165-71-2)

Guidance literature:

DOI:10.1021/ja01631a094

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + phosphonic acid diethyl ester (762-04-9) → hexadecanphosphonic acid diethyl ester (16165-71-2)

Guidance literature:

With 2,2'-azobis(isobutyronitrile);

DOI:10.1021/jo01076a035

upstream raw materials:

hexadecanyl bromide

triethyl phosphite

oct-1-ene

phosphonic acid diethyl ester

Downstream raw materials:

hexadecylphosphonic acid

octadecyl-phosphonic acid monomethyl ester