Sodium hexafluorophosphate

Base Information

• Chemical Name: Sodium hexafluorophosphate
• CAS No.: 21324-39-0
• Molecular Formula: NaPF6
• Molecular Weight: 167.95
• Hs Code.: 28269090
• European Community (EC) Number: 244-333-1
• ChEMBL ID: CHEMBL3327018
• DSSTox Substance ID: DTXSID30943875
• Wikidata: Q2937970
• Wikipedia: Sodium_hexafluorophosphate
• Mol file: 21324-39-0.mol

Synonyms:Sodium hexafluorophosphate;21324-39-0;sodium hexafluorophosphate(v);NaPF6;SODIUMHEXAFLUOROPHOSPHATE;MFCD00011122;sodium hexaflurophosphate;CHEMBL3327018;DTXSID30943875;CHEBI:172377;KMADQUOCJBLXRP-UHFFFAOYSA-N;AKOS015833779;SB66346;Sodium hexafluorophosphate Battery grade;CS-0130517;FT-0655060;NS00083474;phosphate(1-), hexafluoro-, sodium (1:1);S0392;J-013993;Q2937970;Sodium hexafluorophosphate 99% (99.99%-Na) PURATREM;Sodium hexafluorophosphate 99% (99.99%-Na) PURATREM (<10ppm H2O)

Chemical Property of Sodium hexafluorophosphate

Chemical Property:

• Appearance/Colour: solid
• Melting Point: >200 °C(lit.)
• PSA: 13.59000
• Density: 2.369 g/mL at 25 °C(lit.)
• LogP: 3.38240
• Sensitive.: Hygroscopic
• Solubility.: H2O: soluble5%, clear, colorless
• Water Solubility.: SOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 167.95395025
• Heavy Atom Count: 8
• Complexity: 67.1

Purity/Quality:

99% ^*data from raw suppliers

Sodium hexafluorophosphate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,Xi
• Hazard Codes: C,Xi
• Statements: 20/21/22-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: F[P-](F)(F)(F)(F)F.[Na+]
• Uses: Sodium hexafluorophosphate? is a kind of high purity battery grade material, used as an electrolyte in research for sodium ion batteries. Sodium hexafluorophosphate is used as an ion pairing agent for the determination of cobalt(II) in water samples. It is used as an important raw material in the preparation of 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluorophosphate. Sodium hexafluorophosphate is used as an ion pairing agent for the determination of trace cobalt (II) in water samples.

Refernces

Catalytic homogeneous CH-activation reactions of cyclooctane with [Ir(cod)LL]X complexes (LL = N,N-chelating ligands, amines, phosphines; X = Cl, PF₆)

10.1016/j.molcata.2008.01.023

The research focuses on the synthesis and application of novel [Ir(cod)LL]X complexes, where LL represents various chelating ligands, amines, and phosphines, and X denotes Cl or PF6. These iridium complexes were designed to catalyze the selective homogeneous dehydrogenation of cyclooctane to produce cyclooctene, a reaction that was found to be highly dependent on the ligand structure and temperature. The study involved the preparation of different iridium complexes and testing their catalytic activity and selectivity under various conditions. Reactants included [Ir(cod)Cl]2, NaPF6, and a range of ligands, while analyses were performed using techniques such as NMR spectroscopy, mass spectrometry, gas chromatography (GC), and elemental analysis to characterize the complexes and monitor the progress of the dehydrogenation reactions. The experiments also explored the influence of external additives like amines and phosphines on the catalytic performance, with the aim of enhancing the activities of the catalysts.

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