Di-tert-pentyl disulphide

Base Information

• Chemical Name: Di-tert-pentyl disulphide
• CAS No.: 34965-30-5
• Molecular Formula: C10H22 S2
• Molecular Weight: 206.417
• Hs Code.: 2930909090
• European Community (EC) Number: 252-303-4
• DSSTox Substance ID: DTXSID60188510
• Nikkaji Number: J150.807E
• Wikidata: Q83060320
• Mol file: 34965-30-5.mol

Synonyms:Di-tert-pentyl disulphide;34965-30-5;2-methyl-2-(2-methylbutan-2-yldisulfanyl)butane;EINECS 252-303-4;di-tert-amyl disulfide;Disulfide, bis(1,1-dimethylpropyl);DI-TERT-AMYLDISULFIDE;Di-tert-amyl persulfide;SCHEMBL775632;OGTZMPFMCIZSIB-UHFFFAOYSA-;DTXSID60188510;2-Methyl-2-(tert-pentyldisulfanyl)butane #

Chemical Property of Di-tert-pentyl disulphide

Chemical Property:

• Vapor Pressure: 0.0363mmHg at 25°C
• Boiling Point: 249.4°Cat760mmHg
• Flash Point: 67.3°C
• PSA: 50.60000
• Density: 0.931g/cm³
• LogP: 4.74500
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 206.11629305
• Heavy Atom Count: 12
• Complexity: 112

Purity/Quality:

99% ^*data from raw suppliers

DI-TERT-AMYL DISULFIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(C)(C)SSC(C)(C)CC

Technology Process of Di-tert-pentyl disulphide

There total 2 articles about Di-tert-pentyl disulphide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1,1-dimethylpropanethiol (1679-09-0) → bis-(1,1-dimethyl-propyl)-disulfane (34965-30-5)

Guidance literature:

With sodium hydroxide; tetrasodium salt; cobalt tetrasulphophthalocyanine; oxygen; In water; at 20 ℃; for 2.5h; under 760 Torr;

DOI:10.1081/SCC-120003604

Reference yield:

1,1-dimethylpropanethiol (1679-09-0) + 1-(N,N-dimethylamino)-2,3-dichloropropane hydrochloride (50786-84-0) → nereistoxin (1631-58-9) + bis-(1,1-dimethyl-propyl)-disulfane (34965-30-5) + [2-(1,1-Dimethyl-propyldisulfanyl)-1-(1,1-dimethyl-propyldisulfanylmethyl)-ethyl]-dimethyl-amine + [1-[2-Dimethylamino-3-(1,1-dimethyl-propyldisulfanyl)-propyldisulfanylmethyl]-2-(1,1-dimethyl-propyldisulfanyl)-ethyl]-dimethyl-amine

Guidance literature:

With sodium hydroxide; sodium thiosulfate; sodium chloride; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1) EtOH, H₂O, reflux, 30 min., 2) H₂O, CHCl₃, 7 h;

upstream raw materials:

1,1-dimethylpropanethiol

1-(N,N-dimethylamino)-2,3-dichloropropane hydrochloride

Refernces

• 1、 Muehlstaedt, M.,Heinicke, J.,Schubert H.. "A New Group of Compounds Derived from Nereistoxin - Synthesis of Bis-dimethylamino-tris-disulfanes". . p. 841 - 847. Retrieved 2007/10/02.